91. When electric current is passed through an ionic hydride in molten state :

A hydrogen is liberated at anode
B hydrogen is liberated at cathode
C hydride ion migrates towards cathode
D hydride ion remains is solution
Answer :   hydrogen is liberated at anode
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92. From the following statements regarding $${H_2}{O_2},$$  choose the incorrect statement :

A It has to be stored in plastic or wax lined glass bottles in dark
B It has to be kept away from dust
C It can act only as an oxidizing agent
D It decomposes on exposure to light
Answer :   It can act only as an oxidizing agent
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93. Which of the following represents the chemical equation involved in the preparation of $${H_2}{O_2}$$  from barium peroxide?

A $$Ba{O_2} \cdot 8{H_2}O + {H_2}S{O_4} \to $$     $$BaS{O_4} + {H_2}{O_2} + 8{H_2}O$$
B $$C{H_3}CHOHC{H_3} + {O_2} \to $$      $$C{H_3}COC{H_3} + {H_2}{O_2}$$
C $$Ba{O_2} + C{O_2} + {H_2}O \to $$     $$BaC{O_3} + {H_2}{O_2}$$
D $$B{a_3}{\left( {P{O_4}} \right)_2} + 3{H_2}S{O_4} \to $$      $$3BaS{O_4} + 2{H_3}P{O_4}$$
Answer :   $$Ba{O_2} \cdot 8{H_2}O + {H_2}S{O_4} \to $$     $$BaS{O_4} + {H_2}{O_2} + 8{H_2}O$$
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94. Hydrolysis of $$SiC{l_4}$$  gives

A $$SiOC{l_2}$$
B $$Si{O_2}$$
C $${H_2}Si{O_4}$$
D $${\text{none of these}}$$
Answer :   $$Si{O_2}$$
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95. The dielectric constant of $${H_2}O$$  is $$80.$$  The electrostatic force of attraction between $$N{a^ + }$$  and $$C{l^ - }$$  will be

A reduced to $$\frac{1}{{40}}$$  in water than in air
B reduced to $$\frac{1}{{80}}$$ in water than in air
C will be increased to 80 in water than in air
D will remain unchanged.
Answer :   reduced to $$\frac{1}{{80}}$$ in water than in air
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96. The formula for permutit or zeolite which is used as softner in ion-exchange method is

A $$NaAlSi{O_4}$$
B $$NaAl{O_2}$$
C $$C{a_3}{\left( {P{O_4}} \right)_2}$$
D $$N{a_2}S{O_4}$$
Answer :   $$NaAlSi{O_4}$$
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97. Carbon hydrides of the type, $${C_n}{H_{2n + 2}}$$  do not act as Lewis acid or Lewis base. They behave as normal covalent hydrides because

A carbon hydrides are electron - rich hydrides
B carbon hydrides are electron - deficient hydrides
C carbon hydrides are electron - precise hydrides
D carbon hydrides are non - stoichiometric hydrides
Answer :   carbon hydrides are electron - precise hydrides
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98. What happens when an alkaline solution of potassium ferricyanide is reacted with $${H_2}{O_2}?$$

A Potassium ferricyanide is oxidised to potassium ferrocyanide and $${H_2}{O_2}$$  is oxidised to $${O_2}.$$
B Potassium ferricyanide becomes colourless and $${H_2}{O_2}$$  is oxidised to $${O_2}.$$
C Potassium ferricyanide is reduced to ferric hydroxide and $${H_2}{O_2}$$  is oxidised to $${H_2}O.$$
D Potassium ferricyanide is reduced to potassium ferrocyanide and $${H_2}{O_2}$$  is oxidised to $${O_2}.$$
Answer :   Potassium ferricyanide is reduced to potassium ferrocyanide and $${H_2}{O_2}$$  is oxidised to $${O_2}.$$
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99. Which of the following statements are correct ?
i) Hydrogen peroxide is industrially prepared by the auto-oxidation of 2-alkyl anthraquinols
(ii) One millilitre of $$30\% \,{H_2}{O_2}$$   means that solution will give $$100\,V$$  of oxygen at $$STP$$
(iii) Dihedral angle of $${H_2}{O_2}$$  in gas phase is $${90.2^ \circ }$$  and in solid phase dihedral angle is $${111.5^ \circ }$$

A (i), (ii) and (iii)
B (i) and (iii)
C (ii) and (iii)
D (i) and (ii)
Answer :   (i) and (ii)
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100. Consider the following statements :
1. Atomic hydrogen is obtained by passing hydrogen through an electric arc.
2. Hydrogen gas will not reduce heated aluminium oxide.
3. Finely divided palladium adsorbs large volume of hydrogen gas
4. Pure nascent hydrogen is best obtained by reacting $$Na$$  with $${C_2}{H_5}OH$$
Which of the above statements is/are correct ?

A 1 alone
B 2 alone
C 1, 2 and 3
D 2, 3 and 4
Answer :   1, 2 and 3
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