1. If uncertainty principle is applied to an object of mass 1 milligram, the uncertainty value of velocity and position will be

A $$0.2 \times {10^{ - 4}}\,{m^2}\,{s^{ - 1}}$$
B $$0.52 \times {10^6}\,{m^2}\,{s^{ - 1}}$$
C $$0.52 \times {10^{ - 28}}\,{m^2}\,{s^{ - 1}}$$
D $$2 \times {10^{ - 34}}\,{m^2}\,{s^{ - 1}}$$
Answer :   $$0.52 \times {10^{ - 28}}\,{m^2}\,{s^{ - 1}}$$
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2. Any $$p-$$orbital can accommodate upto

A four electrons
B six electrons
C two electrons with parallel spins
D two electrons with opposite spins
Answer :   two electrons with opposite spins
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3. The $$L{i^{2 + }}\,ion$$   is moving in the third stationary state, and its linear momentum is $$7.3 \times {10^{ - 34}}kgm{s^{ - 1}}.$$    Angular momentum is.

A $$1.158 \times {10^{ - 45}}kg\,{m^2}{s^{ - 1}}$$
B $$11.58 \times {10^{ - 48}}kg\,{m^2}{s^{ - 1}}$$
C $$11.58 \times {10^{ - 47}}kg\,{m^2}{s^{ - 1}}$$
D $$12 \times {10^{ - 45}}kg\,{m^2}{s^{ - 1}}$$
Answer :   $$11.58 \times {10^{ - 48}}kg\,{m^2}{s^{ - 1}}$$
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4. If the nitrogen atom has electronic configuration $$1{s^7},$$ it would have energy lower than that of the normal ground state configuration $$1{s^2}2{s^2}2{p^3},$$   because the electrons would be closer to the nucleus. Yet $$1{s^7}$$ is not observed because it violates.

A Heisenberg uncertainty principle
B Hund's rule
C Pauli exclusion principle
D Bohr postulate of stationary orbits
Answer :   Pauli exclusion principle
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5. Which of the following types of spectrum is best depicted by the given figure ?
Atomic Structure mcq question image

A Atomic absorption spectra
B Atomic emission spectra
C Continuous spectra
D None of these
Answer :   Atomic emission spectra
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6. The position of both, an electron and a helium atom is known within $$1.0\,nm.$$  Further the momentum of the electron is known within $$5.0 \times {10^{ - 26}}kg\,m{s^{ - 1}}.$$    The minimum uncertainty in the measurement of the momentum of the helium atom is

A $$50\,kg\,m{s^{ - 1}}$$
B $$80\,kg\,m{s^{ - 1}}$$
C $$8.0 \times {10^{ - 26}}kg\,m{s^{ - 1}}$$
D $$5.0 \times {10^{ - 26}}kg\,m{s^{ - 1}}$$
Answer :   $$5.0 \times {10^{ - 26}}kg\,m{s^{ - 1}}$$
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7. An electron can enter into the orbital when

A value of $$n$$ is minimum
B value of $$l$$ is minimum
C value of $$\left( {n + l} \right)$$  is minimum
D value of $$\left( {n + m} \right)$$  is minimum.
Answer :   value of $$\left( {n + l} \right)$$  is minimum
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8. Which of the following is not a correct statement regarding the energies of orbitals ?

A The lower the value of $$\left( {n + l} \right)$$  for an orbital, lower is its energy.
B Electrons in the same subshell have equal energy.
C Energy of $$s$$ - orbital is lower than the $$p$$ - orbital and that of $$p$$ - orbital is lower than the $$d$$ - orbital.
D If two orbitals have same value for $$\left( {n + l} \right),$$  the orbital with higher value of $$n$$ will have lower energy.
Answer :   If two orbitals have same value for $$\left( {n + l} \right),$$  the orbital with higher value of $$n$$ will have lower energy.
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9. What will be the mass of a particle if uncertainty in its posttton is $${10^{ - 8}}\,m$$   and velocity is $$5.26 \times {10^{ - 25}}\,m\,{s^{ - 1}}\,?$$

A 0.01$$\,kg$$
B 0.1$$\,kg$$
C 1$$\,kg$$
D 10$$\,kg$$
Answer :   0.01$$\,kg$$
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10. An electron, $${e_1}$$ is moving in the fifth stationary state, and another electron $${e_2}$$ is moving in the fourth stationary state. The radius of orbit of electron, $${e_1}$$ is five times the radius of orbit of electron, $${e_2}$$ calculate the ratio of velocity of electron $${e_1}\left( {{v_1}} \right)$$   to the velocity of electron $${e_2}\left( {{v_2}} \right).$$

A 5 : 1
B 4 : 1
C 1 : 5
D 1 : 4
Answer :   1 : 4
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