161.
Water plays a key role in the biosphere. It is due to certain properties of $${H_2}O$$ as compared to other liquids. These are except
A
higher specific heat
B
lesser thermal conductivity
C
high dielectric constant
D
high surface tension
Answer :
lesser thermal conductivity
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Water has higher thermal conductivity, specific heat. dielectric constant and surface tension in comparison to other liquids.
162.
$$100\,mL$$ of $$0.01\,M\,KMn{O_4}$$ oxidises $$100\,mL\,{H_2}{O_2}$$ in acidic medium. Volume of the same $$KMn{O_4}$$ required in alkaline medium to oxidise $$100\,mL$$ of the same $${H_2}{O_2}$$ will be ( $$MnO_4^ - $$ changes to $$M{n^{2 + }}$$ in acidic medium and to $$Mn{O_2}$$ in alkaline medium )
A
$$\frac{{100}}{3}\,mL$$
B
$$\frac{{500}}{3}\,mL$$
C
$$\frac{{300}}{5}mL$$
D
$${\text{None}}$$
Answer :
$$\frac{{500}}{3}\,mL$$
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$$\eqalign{
& MnO_4^ - + 5{e^ - } \to M{n^{2 + }}\,\,{\text{(acidic)}} \cr
& MnO_4^ - + 3{e^ - } \to Mn{O_2}\,{\text{(basic)}} \cr
& 100\,mL\,{H_2}{O_2} \equiv 100 \times 5N \cr
& MnO_4^ - \equiv V \times 3N\,Mn{O_2} \cr
& N = \frac{{500}}{3}mL \cr} $$
163.
A deuterium is
A
an electron with a positive charge
B
a nucleus having two protons
C
a nucleus containing a neutron and two protons
D
a nucleus containing a neutron and a proton
Answer :
a nucleus containing a neutron and a proton
164.
Which of the following is not true ?
A
$${D_2}O$$ freezes at lower temperature than $${H_2}O$$
B
Reaction between $${H_2}$$ and $$C{l_2}$$ is much faster than $${D_2}$$ and $$C{l_2}$$
C
Ordinary water gets electrolysed more rapidly than $${D_2}O$$
D
Bond dissociation energy of $${D_2}$$ is greater than $${H_2}$$
Answer :
$${D_2}O$$ freezes at lower temperature than $${H_2}O$$
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$${D_2}O$$ actually has higher freezing point $$\left( {{{3.8}^ \circ }C} \right)$$ than water $${H_2}O\left( {{0^ \circ }C} \right)$$
165.
In which of the following properties hydrogen does not show similarity with alkali metals?
A
Electropositive character
B
Reducing nature
C
Electronic configuration $$\left( {n{s^1}} \right)$$
D
Diatomic nature of molecule
Answer :
Diatomic nature of molecule
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Hydrogen forms a diatomic molecule similar to halogens but alkali metals are monoatomic.
166.
Which of the following is not true?
A
Ordinary water is electrolysed more rapidly than $${D_2}O.$$
B
Reaction between $${H_2}$$ and $$C{l_2}$$ is much faster than $${D_2}$$ and $$C{l_2}.$$
C
$${D_2}O$$ freezes at lower temperature than $${H_2}O.$$
D
Bond dissociation energy for $${D_2}$$ is greater than $${H_2}.$$
Answer :
$${D_2}O$$ freezes at lower temperature than $${H_2}O.$$
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$${D_2}O$$ has higher freezing point than that of water.
167.
Hydrogen peroxide in its reaction with $$KI{O_4}\,{\text{and}}\,N{H_2}OH$$ respectively, is acting as a
A
Reducing agent, oxidising agent
B
Reducing agent, reducing agent
C
Oxidising agent, oxidising agent
D
Oxidising agent, reducing agent
Answer :
Reducing agent, oxidising agent
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$$\eqalign{
& KI{O_4} + {H_2}{O_2} \to KI{O_3} + {H_2}O + {O_2} \cr
& {\text{Thus}}\,{H_2}{O_2}\,{\text{is}}\,{\text{acting}}\,{\text{as}}\,{\text{a}}\,{\text{reducing}}\,{\text{agent}} \cr
& 2N{H_2}OH + {H_2}{O_2} \to {N_2} + 4{H_2}O \cr
& {\text{Here}}\,{H_2}{O_2}\,{\text{is}}\,{\text{acting}}\,{\text{as}}\,{\text{an}}\,{\text{oxidising}}\,{\text{agent}} \cr} $$
168.
Elements of which of the following group(s) of periodic table do not form hydrides.
A
Groups 7, 8, 9
B
Group 13
C
Groups 15, 16, 17
D
Group 14
Answer :
Groups 7, 8, 9
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The metals of group 7, 8 and 9 do not form hydrides.
169.
In what respect electronic configuration of hydrogen and halogens are similar?
A
Hydrogen and halogens have one electron in their outermost shell.
B
Hydrogen and halogens have one electron less than the noble gas configuration.
C
Hydrogen and halogens can lose one electron to form positive ions.
D
Hydrogen and halogens show noble gas configuration.
Answer :
Hydrogen and halogens have one electron less than the noble gas configuration.
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$$H - 1{s^1};He - 1{s^2}$$
Halogen, $$X - n{s^2}n{p^5};$$ Inert gas $$ - n{s^2}n{p^6}$$
Both have one electron less than the nearest noble gas configuration.
170.
Water gas is mixed with steam and the mixture is passed over heated $$F{e_2}{O_3}$$ in presence of $$C{r_2}{O_3}.$$ The mixture when passed in water dissolves $$C{O_2}$$ and dihydrogen left undissolved is collected. This method of preparation of hydrogen gas is known as
A
Bosch process
B
Lane process
C
Kellner process
D
Hall process
Answer :
Bosch process
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Bosch process is used to prepare di-hydrogen commercially. In this process water gas prepared from coal & water at $$1270\,K$$ is mixed with two times its volume of steam passed over $$F{e_2}{O_3}$$ in presence of promoter $$C{r_2}{O_3}.$$