281.
What happens when a mixture of cobalt oxide and borax is heated in a flame on a loop of platinum wire?
A
A transparent white bead is formed.
B
A bright pink coloured $$NaB{O_2}$$ bead is formed.
C
A blue coloured $$Co{\left( {B{O_2}} \right)_2}$$ bead is formed.
D
A red coloured $$Co{\left( {B{O_2}} \right)_2}$$ bead is formed.
Answer :
A blue coloured $$Co{\left( {B{O_2}} \right)_2}$$ bead is formed.
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\[N{{a}_{2}}{{B}_{4}}{{O}_{7}}\cdot 10{{H}_{2}}O\xrightarrow{\Delta }N{{a}_{2}}{{B}_{4}}{{O}_{7}}\] \[\xrightarrow{\Delta }2NaB{{O}_{2}}+{{B}_{2}}{{O}_{3}}\]
\[{{B}_{2}}{{O}_{3}}+CoO\to \underset{\begin{smallmatrix}
\text{Cobalt metaborate} \\
\text{(blue bead)}
\end{smallmatrix}}{\mathop{Co{{\left( B{{O}_{2}} \right)}_{2}}}}\,\]
282.
Which is the most thermodynamically stable allotropic form of phosphorus?
A
red
B
white
C
black
D
yellow
Answer :
black
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The ignition temperature of black phosphorus is highest among all its allotropes, hence is most stable.
283.
Which of the following pairs is not correctly matched?
A
Allotropic form of sulphur which is more stable at room temperature - Rhombic
B
The hydride of group 16 which is liquid at room temperature - Water
C
The gas formed in the upper layers of atmosphere by action of $$UV$$ radiations - Nitrogen
D
The catalyst used in the manufacture of $${H_2}S{O_4}$$ by contact process - Vanadium pentoxide
Answer :
The gas formed in the upper layers of atmosphere by action of $$UV$$ radiations - Nitrogen
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The gas formed in the upper layers of atmosphere by action of $$UV$$ radiations is ozone.
284.
Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen?
A
$$HN{O_3},NO,N{H_4}Cl,{N_2}$$
B
$$\,HN{O_3},NO,{N_2},N{H_4}Cl$$
C
$$HN{O_3},N{H_4}Cl,NO,{N_2}$$
D
$$NO,HN{O_3},N{H_4}Cl,{N_2}$$
Answer :
$$\,HN{O_3},NO,{N_2},N{H_4}Cl$$
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$$HN\mathop {{O_3}}\limits^{ + 5} ,\mathop N\limits^{ + 2} O,\mathop {{N_2}}\limits^0 ,\mathop N\limits^{ - 3} {H_4}Cl$$
285.
Strong reducing behaviour of $${H_3}P{O_2}$$ is due to
A
presence of one $$—OH$$ group and two $$P—H$$ bonds
B
high electron gain enthalpy of phosphorus
C
high oxidation state of phosphorus
D
presence of two $$—OH$$ groups and one $$P—H$$ bond
Answer :
presence of one $$—OH$$ group and two $$P—H$$ bonds
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The oxy acid of phosphorus which contain $$P—H$$ bond act as a reducing agent or reductant.
In $${H_3}P{O_2}$$ one $$—OH$$ group and two $$P—H$$ bonds are present.
286.
Which among the following is paramagnetic?
A
$$C{l_2}O$$
B
$$Cl{O_2}$$
C
$$C{l_2}{O_7}$$
D
$$C{l_2}{O_6}$$
Answer :
$$Cl{O_2}$$
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$$Cl{O_2}$$ contains total valence electrons 19,
7 valence electrons of $$Cl$$
6 valence electrons of one oxygen atom
So there must be unpaired electron, thus it is paramagnetic in nature.
287.
Which of the following oxy-acids has the maximum number of hydrogens directly attached to phosphorus ?
A
$${H_4}{P_2}{O_7}$$
B
$${H_3}P{O_2}$$
C
$${H_3}P{O_3}$$
D
$${H_3}P{O_4}$$
Answer :
$${H_3}P{O_2}$$
288.
When steam reacts with red hot coke to form $$C{O_2}$$ and hydrogen :
A
Water acts as an oxidising agent.
B
Water acts as a reducing agent.
C
Carbon acts as an oxidising agent.
D
There is no oxidation or reduction.
Answer :
Water acts as an oxidising agent.
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$$\eqalign{
& \mathop {{H_2}O}\limits_{{\text{Steam}}} + C \to C{O_2} + {H_2} \cr
& {H_2}O\,\,{\text{oxidises}}\,\,C \to C{O_2}, \cr
& {\text{hence }}{H_2}O{\text{ acts as oxidising agent}}{\text{.}} \cr} $$
289.
On heating ammonium dichromate, the gas evolved is
A
oxygen
B
ammonia
C
nitrous oxide
D
nitrogen
Answer :
nitrogen
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$${\left( {N{H_4}} \right)_2}C{r_2}{O_7} \to {N_2} + C{r_2}{O_3} + 4{H_2}O$$
290.
Pick out the wrong statement.
A
Nitrogen has the ability to form $$p\pi - p\pi $$ bonds with itself.
B
Bismuth forms metallic bonds in elemental state.
C
Catenation tendency is higher in nitrogen when compared with other elements of the same group.
D
Nitrogen has higher first ionisation enthalpy when compared with other elements of the same group.
Answer :
Catenation tendency is higher in nitrogen when compared with other elements of the same group.
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Catenation tendency is higher in phosphorus when compared with other elements of same group.