On moving, down the group the size increases and electronegativity decreases, thus tendency to show catenation decreases. Decrease in catenation property is linked with $$M - M$$ bond enthalpy which decreases from carbon to tin.
262.
Arrange the following hydrides of group 16 elements in order of increasing stability.
There is a decrease in bond enthalpy $$(H - E)$$ as the size of the element increases on moving down the group hence, the stability decreases on moving down the group.
263.
Which is not a method of preparing carbon monoxide on a commercial scale?
A
\[C+{{H}_{2}}O\xrightarrow{473-1273\,K}CO+{{H}_{2}}\]
B
\[2C+{{O}_{2}}+4{{N}_{2}}\xrightarrow{1273\,K}2CO+4{{N}_{2}}\]
C
\[2C+{{O}_{2}}\xrightarrow{\Delta }2CO\]
D
\[HCOOH\xrightarrow[conc.\,{{H}_{2}}S{{O}_{4}}]{373\,K}{{H}_{2}}O+CO\]
The $$H - X$$ bond strength decreases from $$HF\,{\text{to}}\,HI$$. i.e. $$HF > HCl > HBr > HI.$$ Thus $$HF$$ is most stable while $$HI$$ is least stable. This is evident from their decomposition reaction: $$HF\,{\text{and}}\,HCl$$ are stable upto $$1473K,$$ $$HBr$$ decreases slightly and $$HI$$ dissociates considerably at $$713K.$$ The decreasing stability of the hydrogen halide Oxidation is also reflected in the values of dissociation energy of $$H - X$$ bond
$$\mathop {H - F}\limits_{135kcal\,mo{l^{ - 1}}} \,\,\mathop {H - Cl}\limits_{103kcal\,mo{l^{ - 1}}} \,\,\,\,\,\,\,\mathop {H - Br}\limits_{87kcal\,mo{l^{ - 1}}} \,\,\,\,\,\,\mathop {H - I}\limits_{71kcal\,mo{l^{ - 1}}} $$
268.
Which of the following is not an ore of aluminium?
Acidic strength of oxoacids of a particular halogen atom increases with increase in oxidation number, thus the order of acidic strength is
$$\mathop {HClO}\limits^{ + 1} < \mathop {HCl{O_2}}\limits^{ + 3} < \mathop {HCl{O_3}}\limits^{ + 5} < \mathop {HCl{O_4}}\limits^{ + 7} .$$