Holme's signal uses calcium carbide and calcium phosphide. The spontaneous combustion of phosphine is technically used in Holme's signals. Containers containing a mixture of calcium carbide and calcium phosphide are pierced and thrown in the sea when the gases burn and serve as a Signal.
342.
Hot concentrated sulphuric acid is a moderately strong oxidising agent. Which of the following reaction does not show oxidising behaviour?
A
$$Cu + 2{H_2}S{O_4} \to CuS{O_4} + S{O_2} + 2{H_2}O$$
B
$$3S + 2{H_2}S{O_4} \to 3S{O_2} + 2{H_2}O$$
C
$$C + 2{H_2}S{O_4} \to C{O_2} + 2S{O_2} + 2{H_2}O$$
Key Idea An oxidising agent is a species, which oxidises the other species and itself gets reduced.
\[\begin{align}
& \left( \text{i} \right)C\overset{0}{\mathop{u}}\,+2{{H}_{2}}S{{O}_{4}}\to \overset{+2}{\mathop{Cu}}\,S{{O}_{4}}+S{{O}_{2}}+2{{H}_{2}}O \\
& \left( \text{ii} \right)3\overset{0}{\mathop{S}}\,+2{{H}_{2}}S{{O}_{4}}\to \overset{+4}{\mathop{3S{{O}_{2}}}}\,+2{{H}_{2}}O \\
& \left( \text{iii} \right)\overset{0}{\mathop{C}}\,+{{H}_{2}}S{{O}_{4}}\to \overset{+4}{\mathop{C{{O}_{2}}}}\,+2S{{O}_{2}}+2{{H}_{2}}O \\
& \left( \text{iv} \right)\overset{+2}{\mathop{C}}\,a{{\overset{-1}{\mathop{F}}\,}_{2}}+{{H}_{2}}S{{O}_{4}}\to \overset{+2}{\mathop{Ca}}\,S{{O}_{4}}+2H\overset{-1}{\mathop{F}}\, \\
\end{align}\]
In reaction (iv), oxidation number of elements remains unchanged. Thus, in this reaction, $${H_2}S{O_4}$$ does not act as an oxidising agent.
343.
A solution of $$KBr$$ is treated with each of the following. Which one would liberate bromine?
$$\,HI$$ and $$HBr$$ (in that order) are the strongest reducing
hydracids and hence they reduce $${H_2}S{O_4}$$ . $$HCl$$ is quite stable and hence is oxidised by strong oxidising agent like $$KMn{O_4}$$ . $$HF$$ is not a reducing agent. In the smallest
$${F^ - }$$ ion, the electron which is to be removed during oxidation is closest to the nucleus and therefore most difficult to be removed. Therefore, $$HF$$ is a poor reducing agent.
346.
The stability of +1 oxidation state among $$Al,Ga,In$$ and $$Tl$$ increases in the sequence
$$Al < Ga < In < Tl$$
This is due to inert pair effect or tendency of $$n{s^2}$$ electrons do not participate in bond formation. This tendency decreases on moving down the group.
347.
Which of the following statement $$(s)$$ is / are incorrect for $$C{O_2}?$$
(i) In laboratory $$C{O_2}$$ is prepared by the action of dilute $$HCl$$ on calcium carbonate
(ii) Carbon dioxide is a poisonous gas
(iii) Increase in carbon dioxide content in atmosphere lead to increase in green house effect.
(iv) $$C{O_2}$$ as dry ice is used as a refrigerant for ice cream and frozen food.
$$ICl$$
Order of reactivity of halogens
$$C{l_2} > B{r_2} > {I_2}$$
But, the interhalogen compounds are generally more reactive than halogens $$({\text{expect}}\,{F_2})$$ , since the bond between two dissimilar electronegative elements is weaker than the bond between two similar atoms i.e, $$X - X$$