301. In solid state $$PC{l_5}$$  is a ________.

A covalent solid
B octahedral structure
C ionic solid with $${\left[ {PC{l_6}} \right]^ + }$$  octahedral and $${\left[ {PC{l_4}} \right]^ - }$$  tetrahedral
D ionic solid with $${\left[ {PC{l_4}} \right]^ + }$$  tetrahedral and $${\left[ {PC{l_6}} \right]^ - }$$  octahedral
Answer :   ionic solid with $${\left[ {PC{l_4}} \right]^ + }$$  tetrahedral and $${\left[ {PC{l_6}} \right]^ - }$$  octahedral
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302. $$A{l_2}{O_3}$$   can be converted into anhydrous $$AlC{l_3}$$  by heating

A $$A{l_2}{O_3}$$  with $$HCl$$  gas
B $$A{l_2}{O_3}$$  with $$NaCl$$  in solid state
C a mixture of $$A{l_2}{O_3}$$  and carbon in dry $$C{l_2}$$  gas
D $$A{l_2}{O_3}$$  with $$C{l_2}$$  gas.
Answer :   a mixture of $$A{l_2}{O_3}$$  and carbon in dry $$C{l_2}$$  gas
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303. $${P_2}{O_5}$$  is heated with water to give

A hypophosphorous acid
B phosphorous acid
C hypophosphoric acid
D orthophosphoric acid
Answer :   orthophosphoric acid
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304. To a piece of charcoal, sulphuric acid is added. Then :

A there is no reaction
B water gas is formed
C $$S{O_2}$$  and $$C{O_2}$$  are evolved
D $$CO$$  and $$S{O_2}$$  are evolved
Answer :   $$S{O_2}$$  and $$C{O_2}$$  are evolved
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305. Heating an aqueous solution of aluminium chloride to dryness will give

A $$Al\left( {OH} \right)C{l_2}$$
B $$A{l_2}{O_3}\,$$
C $$A{l_2}C{l_6}$$
D $$AlC{l_3}$$
Answer :   $$A{l_2}{O_3}\,$$
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306. When sugar is treated with $$conc.$$  sulphuric acid, the sugar is charred. In this process, sugar is

A reduced
B oxidized
C sulphonated
D dehydrated
Answer :   dehydrated
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307. Which one of the following statement regarding helium is incorrect?

A It is used to produce and sustain powerful superconducting magnets
B It is used as a cryogenic agent for carrying out experiments at low temperatures
C It is used to fill gas balloons instead of hydrogen because it is lighter and non-inflammable
D It is used in gas-cooled nuclear reactors
Answer :   It is used to fill gas balloons instead of hydrogen because it is lighter and non-inflammable
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308. Among the following molecules,
$$\eqalign{ & \left( {\text{i}} \right)Xe{O_3} \cr & \left( {{\text{ii}}} \right)XeO{F_4} \cr & \left( {{\text{iii}}} \right)Xe{F_6} \cr} $$
those having same number of lone pairs on $$Xe$$  are

A (i) and (ii) only
B (i) and (iii) only
C (ii) and (iii) only
D (i), (ii) and (iii)
Answer :   (i), (ii) and (iii)
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309. Which of the following statements is wrong?

A Single $$N-N$$  bond is stronger than the single $$P-P$$  bond.
B $$P{H_3}$$  can act as a ligand in the formation of coordination compound with transition elements.
C $$N{O_2}$$  is paramagnetic in nature.
D Covalency of nitrogen in $${N_2}{O_5}$$  is four.
Answer :   Single $$N-N$$  bond is stronger than the single $$P-P$$  bond.
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310. Which of the following statements is not correct?

A Helium has the lowest boiling point among the noble gases.
B Argon is used in electric bulbs.
C Krypton is obtained during radioactive disintegration.
D $$Xe$$  forms $$Xe{F_6}.$$
Answer :   Krypton is obtained during radioactive disintegration.
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