231.
A substance absorbs $$C{O_2}$$ and voilently reacts with water. The substance is
A
$$CaC{O_3}$$
B
$$CaO$$
C
$${H_2}S{O_4}$$
D
$$ZnO$$
Answer :
$$CaO$$
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\[CaO+{{H}_{2}}O\xrightarrow{\text{Hissing}\,\,\text{sound}}\] \[Ca{{\left( OH \right)}_{2}}+\text{Heat}\]
\[CaO+C{{O}_{2}}\to CaC{{O}_{3}}\]
232.
Calcium is obtained by
A
electrolysis of molten $$CaC{l_2}.$$
B
electrolysis of solution of $$CaC{l_2}$$ in water.
C
Reduction of $$CaC{l_2}$$ with carbon.
D
roasting of limestone.
Answer :
electrolysis of molten $$CaC{l_2}.$$
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$$Ca$$ is obtained by electrolysis ofmolten mixture of $$CaC{l_2}$$ mixed with $$Ca{F_2}.$$
233.
Match the column I with column II and mark the appropriate choice.
Column I
Column II
a.
Quick lime
1.
$$Ca{H_2}$$
b.
Slaked lime
2.
$$Ba{\left( {OH} \right)_2}$$
c.
Baryta water
3.
$$Ca{\left( {OH} \right)_2}$$
d.
Hydrolith
4.
$$CaO$$
A
a - 1, b - 2, c - 3, d - 4
B
a - 3, b - 2, c - 1, d - 4
C
a - 1, b - 3, c - 4, d - 2
D
a - 4, b - 3, c - 2, d - 1
Answer :
a - 4, b - 3, c - 2, d - 1
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234.
Crystalline sodium chloride is a bad conductor of electricity while molten $$NaCl$$ and its aqueous solution conduct electricity. This is because
A
crystalline sodium chloride contains molecules only
B
the ions present in it are not free to move in solid state
C
sodium chloride is a covalent crystal
D
solid substances do not conduct electricity
Answer :
the ions present in it are not free to move in solid state
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$$N{a^ + }$$ and $$C{l^ - }$$ ions are free to move only in molten state or aqueous solution.
235.
In Solvay ammonia process, sodium bicarbonate is precipitated due to
A
presence of $$N{H_3}$$
B
reaction with $$C{O_2}$$
C
reaction with brine solution
D
reaction with $$NaOH$$
Answer :
reaction with brine solution
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In Solvay ammonia process, sodium bicarbonate is precipitated due to common ion $$\left( {N{a^ + }} \right)$$ effect provided by brine ( concentrated $$NaCl$$ solution ).
$$N{H_4}HC{O_3} + NaCl + N{H_4}Cl$$ $$ + NaHC{O_3} \downarrow $$
236.
The pair of compounds which cannot exits together in solution is
A
$$NaHC{O_3}\,{\text{and}}\,NaOH$$
B
$$N{a_2}C{O_3}\,{\text{and}}\,NaHC{O_3}$$
C
$$N{a_2}C{O_3}\,{\text{and}}\,NaOH$$
D
$$NaHC{O_3}\,{\text{and}}\,NaCl$$
Answer :
$$NaHC{O_3}\,{\text{and}}\,NaOH$$
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$$\eqalign{
& NaHC{O_3} + NaOH \to N{a_2}C{O_3} + {H_2}O \cr
& \left( {NaHC{O_3}\,{\text{is an acidic salt}}} \right) \cr} $$
237.
The main oxides formed on combustion of $$Li,Na$$ and $$K$$ in excess of air are, respectively:
A
$$L{i_2}{O_2},N{a_2}{O_2}\,{\text{and}}\,K{O_2}$$
B
$$L{i_2}O,N{a_2}{O_2}\,{\text{and}}\,K{O_2}$$
C
$$L{i_2}O,N{a_2}O\,{\text{and}}\,K{O_2}$$
D
$$Li{O_2},N{a_2}{O_2}\,{\text{and}}\,{K_2}O$$
Answer :
$$L{i_2}O,N{a_2}{O_2}\,{\text{and}}\,K{O_2}$$
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On heating with excess of air $$Li,Na$$ and $$K$$ forms following oxides
\[\begin{align}
& 4Li+{{O}_{2}}\to \underset{\text{Lithium monoxide }}{\mathop{2L{{i}_{2}}O}}\, \\
& 2Na+{{O}_{2}}\xrightarrow{575\,K}\underset{\text{Sodium peroxide }}{\mathop{N{{a}_{2}}{{O}_{2}}}}\, \\
& K+{{O}_{2}}\to \underset{\text{Potassium superoxide}}{\mathop{K{{O}_{2}}}}\, \\
\end{align}\]
238.
Which of the following will have lowest value of $${K_{sp}}$$ at room temperature?
A
$$Be{\left( {OH} \right)_2}$$
B
$$Mg{\left( {OH} \right)_2}$$
C
$$Ca{\left( {OH} \right)_2}$$
D
$$Ba{\left( {OH} \right)_2}$$
Answer :
$$Be{\left( {OH} \right)_2}$$
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$$Be{\left( {OH} \right)_2}$$ is least soluble in water hence, it will have lowest value of $${K_{sp}}.$$
$$Be{\left( {OH} \right)_2} \rightleftharpoons B{e^{2 + }} + 2O{H^ - };$$ $${K_{sp}} = \left[ {B{e^{2 + }}} \right]{\left[ {O{H^ - }} \right]^2}$$
239.
Some of the group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is
A
$$BeC{l_2}$$
B
$$MgC{l_2}$$
C
$$CaC{l_2}$$
D
$$SrC{l_2}$$
Answer :
$$BeC{l_2}$$
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Beryllium halides are essentially covalent and soluble in organic solvents like ethanol.
240.
Match column I with column II and mark the appropriate choice.
Column I
Column II
a.
$$Li$$
1.
$${M_2}{O_2}$$
b.
$$Na$$
2.
$$M{O_2}$$
c.
$$Rb$$
3.
$${M_2}O$$
A
a - 1, b - 2, c - 3
B
a - 3, b - 2, c - 1
C
a - 3, b - 1, c - 2
D
a - 2, b - 3, c - 1
Answer :
a - 3, b - 1, c - 2
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