As $$C{s^ + }\,ion$$ has larger size than $$L{i^ + }$$ and $${I^ - }$$ has larger size than $${F^ - },$$ therefore maximum distance between centres of cations and anions is in $$CsI.$$
143.
Beryllium shows diagonal relationship with aluminium. Which of the following similarity is incorrect?
A
$$B{e_2}C$$ like $$A{l_4}{C_3}$$ yields methane on hydrolysis.
B
$$Be$$ like $$Al$$ is rendered passive by $$HN{O_3}.$$
C
$$Be{\left( {OH} \right)_2}$$ like $$Al{\left( {OH} \right)_3}$$ is basic.
D
$$Be$$ forms beryllates and $$Al$$ forms aluminates.
Answer :
$$Be{\left( {OH} \right)_2}$$ like $$Al{\left( {OH} \right)_3}$$ is basic.
Both $$Be{\left( {OH} \right)_2}$$ and $$Al{\left( {OH} \right)_3}$$ are amphoteric in nature.
144.
A solid compound $$'X'$$ on heating gives $$C{O_2}$$ gas and a residue. The residue mixed with water forms $$'Y'.$$ On passing an excess of $$C{O_2}$$ through $$'Y'$$ in water, a clear solution $$'Z',$$ is obtained. On boiling
$$'Z',$$ compound $$'X'$$ is reformed. The compound $$'X'$$ is
NOTE: Acidicand basic salts cannot exist together. Since $$NaHC{O_3}$$ is an acid salt of $${H_2}C{O_3},$$ it reacts with $$NaOH$$ to form $$N{a_2}C{O_3}$$ and $$\,{H_2}O.$$
$$NaHC{O_3} + NaOH \to N{a_2}C{O_3} + {H_2}O$$
148.
Which of the following is not the point of difference between $$Be$$ and other alkaline earth metals?
A
It has a tendency to form covalent bonds.
B
It dissolves in alkalies with evolution of hydrogen.
C
Its oxides and hydroxides are amphoteric.
D
Its carbide gives acetylene on hydrolysis.
Answer :
Its carbide gives acetylene on hydrolysis.
Down the group from $$Li$$ to $$Cs,$$ the effect of increasing size outweighs the increasing nuclear charge, and the outermost electron is well screened from the nuclear charge.
150.
A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of
The free ammoniated electrons make the solution of $$Na$$ in liquid $$N{H_3}$$ a very powerful reducing agent.
NOTE : The ammonical solution of an alkali metal is rather favoured as a reducing agent than its aqueous solution because in aqueous solution the alkali metal being highly electropositive evolves hydrogen from water (thus $${H_2}O$$ acts as an oxidisng agent) while its solution in ammonia is quite stable, provided no catalyst (transition metal) is present.