181.
Match the column I with column II and mark the appropriate choice.
Column I
Column II
a.
$$Li$$
1.
Role in biological systems
b.
$$K$$
2.
Golden yellow flame
c.
$$Na$$
3.
Photoelectric cell
d.
$$Cs$$
4.
Carbonate decomposes on heating
A
a - 4, b -1 , c - 3, d - 2
B
a - 1, b - 3, c - 2, d - 4
C
a - 3, b - 2, c - 1, d - 4
D
a - 4, b - 1, c - 2, d - 3
Answer :
a - 4, b - 1, c - 2, d - 3
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182.
When sulphur is heated with $$NaOH\left( {aq} \right).$$ The compounds formed are
A
$$N{a_2}S + {H_2}O$$
B
$$N{a_2}S{O_3} + {H_2}O$$
C
$$N{a_2}S + N{a_2}{S_2}{O_3} + {H_2}O$$
D
$$N{a_2}{S_2}{O_3} + {H_2}O$$
Answer :
$$N{a_2}S + N{a_2}{S_2}{O_3} + {H_2}O$$
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$$4S + 6NaOH \to N{a_2}{S_2}{O_3} + 2\,N{a_2}S + 3{H_2}O$$
183.
Which of the following is not present in portland cement?
A
$$C{a_3}A{l_2}{O_6}$$
B
$$C{a_3}Si{O_5}$$
C
$$C{a_2}Si{O_4}$$
D
$$C{a_3}{\left( {P{O_4}} \right)_2}$$
Answer :
$$C{a_3}{\left( {P{O_4}} \right)_2}$$
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Phosphate is not a part of composition of portland cement.
184.
Sulphates of $$Be$$ and $$Mg$$ are readily soluble in water but sulphates of $$Ca, Sr$$ and $$Ba$$ are insoluble. This is due to the fact
A
the greater hydration enthalpies of $$B{e^{2 + }}$$ and $$M{g^{2 + }}$$ overcome the lattice enthalpy
B
high lattice enthalpy of $$B{e^{2 + }}$$ and $$M{g^{2 + }}$$ makes them soluble in water
C
solubility decreases from $$BeS{O_4}$$ to $$BaS{O_4}$$ due to increase in ionic size
D
$$BeS{O_4}$$ and $$MgS{O_4}$$ are ionic in nature while other sulphates are covalent
Answer :
the greater hydration enthalpies of $$B{e^{2 + }}$$ and $$M{g^{2 + }}$$ overcome the lattice enthalpy
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Due to smaller size their lattice enthalpies are high but their greater hydration enthalpies overcome the lattice enthalpies and they become soluble in water. $$Ca, Sr$$ and $$Ba$$ sulphates are insoluble is water due to lower hydration enthalpies.
185.
Match the column I with column II and mark the appropriate choice.
A
A - iv, B - i, C - ii, D - iii
B
A - iv, B - i, C - iii, D - ii
C
A - ii, B - iii, C - iv, D - i
D
A - iii, B - i, C - iv, D - ii
Answer :
A - iii, B - i, C - iv, D - ii
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186.
The substance not likely to contain $$CaC{O_3}$$ is
A
calcined gypsum
B
sea shells
C
dolomite
D
a marble statue
Answer :
calcined gypsum
187.
One mole of magnesium nitride on the reaction with an excess of water gives :
A
two moles of ammonia
B
one mole of nitric acid
C
one mole of ammonia
D
two moles of nitric acid
Answer :
two moles of ammonia
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$$M{g_3}{N_2} + 6{H_2}O \rightleftharpoons 3Mg{\left( {OH} \right)_2} + 2N{H_3}$$
188.
When $$BeC{l_2}$$ is hydrolysed, white fumes of gas are given out. The intensity of fumes intensifies when a rod dipped in moist ammonia is brought near the mouth of the test tube. The gas which comes out during hydrolysis is
A
$$C{l_2}$$
B
$$HCl$$
C
$$N{H_4}OH$$
D
$$N{H_4}Cl$$
Answer :
$$HCl$$
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$$BeC{l_2} + 2{H_2}O \to $$ $$Be{\left( {OH} \right)_2} + \mathop {2HCl}\limits_{\left( {{\text{fumes}}} \right)} $$
$$HCl + N{H_3} \to \mathop {N{H_4}Cl}\limits_{\left( {{\text{intense fumes}}} \right)} $$
189.
Which of the following is most stable ?
A
$$N{a_3}N$$
B
$$L{i_3}N$$
C
$${K_3}N$$
D
$$R{b_3}N$$
Answer :
$$L{i_3}N$$
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Only $$L{i_3}N$$ is stable, others are not formed at all.
190.
The difference of number of water molecules in gypsum and plaster of Paris is
A
$$\frac{5}{1}$$
B
$$2$$
C
$$\frac{1}{2}$$
D
$$1\frac{1}{2}$$
Answer :
$$1\frac{1}{2}$$
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Gypsum is $$\,CaS{O_4}.2{H_2}O,$$ where as plaster of paris is $$\,CaS{O_4}\,\frac{1}{2}{H_2}O.$$
No. of water $$ = \left( {2 - \frac{1}{2}} \right) \to \frac{3}{2}\,{\text{or}}\,1\frac{1}{2}$$ molecules