The dissociation energy will be more when the bond order will be greater and bond order $$ \propto $$ dissociation energy
$${\text{Molecular orbital configuration of}}$$
$${N_2}\left( {14} \right) = \sigma 1{s^2},\mathop \sigma \limits^* 1{s^2},\sigma 1{s^2},$$ $$\mathop \sigma \limits^* 2{s^2},\pi 2p_y^2 \approx \pi 2p_z^2,\sigma 2p_x^2$$
$$\eqalign{
& {\text{So, bond order of}} \cr
& {N_2} = \frac{{{N_b} - {N_a}}}{2} \cr
& \,\,\,\,\,\,\,\, = \frac{{10 - 4}}{2} \cr
& \,\,\,\,\,\,\,\, = 3 \cr
& {\text{and bond order of}} \cr
& N_2^ + = \frac{{9 - 4}}{2} \cr
& \,\,\,\,\,\,\,\,\,\, = 2.5 \cr} $$
As the bond order of $${N_2}$$ is greater than $$N_2^ + $$ so, the dissociation energy of $${N_2}$$ will be greater than $$N_2^ + $$ .
162.
The geometry of $${H_2}S$$ and its dipole moment are
Hybridisation of $$S\,\,in\,\,{H_2}S = \frac{1}{2}\left( {6 + 2 + 0 - 0} \right) = 4$$
∴ $$S$$ has $$s{p^3}$$ hybridisation and $$2$$ lone pair of electrons in $${H_2}S$$
∴ It has angular geometry and so it has non-zero value of dipole moment.
163.
For two ionic solids $$CaO$$ and $$KI$$ , identify the wrong statement among the following.
A
Lattice energy of $$CaO$$ is much larger than that of $$KI$$
$$KI$$ is ionic compound, so it is not soluble in non-polar solvent ( i.e. dipole moment $$\left( \mu \right)$$ for benzene $$ = 0$$ ).
164.
In a diatomic molecule the bond distance is $$1 \times {10^{ - 8}}\,cm.$$ Its dipole moment is $$1.2\,D.$$ What is the fractional electronic charge on each atom?
In (i), the $$lp$$ are at equatorial position so there are less $$lp{\text{ - }}bp$$ repulsions as compared to other positions. Hence, $$T$$ - shape is most stable.
166.
What is the dominant intermolecular force on bond that must be overcome in converting liquid $$C{H_3}OH$$ to a gas?
In between $$C{H_3}OH$$ molecules intermolecular $$H - {\text{bonding}}$$ exist.
Hence, it is the intermolecular $$H - {\text{bonding}}$$ that must be overcome in converting liquid $$C{H_3}OH$$ to gas.
167.
Which of the following compounds shows maximum hydrogen bond strength?
Both $$N{O_2}\,\,{\text{and}}\,\,\,{O_3}$$ have angular shape and hence will have net dipole moment.
170.
Consider the molecules $$C{H_4},N{H_3}$$ and $${H_2}O.$$
Which of the given statements is false?
A
The $$H-O-H$$ bond angle in $${H_2}O$$ is larger than the $$H - C - H$$ bond angle in $$C{H_4}$$
B
The $$H - O - H$$ bond angle in $${H_2}O$$ is smaller than the $$H - N - H$$ bond angle in $$N{H_3}$$
C
The $$H - C - H$$ bond angle in $$C{H_4}$$ is larger than the $$H - N - H$$ bond angle in $$N{H_3}$$
D
The $$H - C - H$$ bond angle in $$C{H_4},$$ the $$H - N - H$$ bond angle in $$N{H_3}$$ and the $$H - O - H$$ bond angle in $${H_2}O$$ are all greater than $${90^ \circ }$$
Answer :
The $$H-O-H$$ bond angle in $${H_2}O$$ is larger than the $$H - C - H$$ bond angle in $$C{H_4}$$
As the number of lone pair of electrons on central element increases, repulsion between those lone pair of electrons increases and therefore, bond angle decreases. Molecules Bond angle
$$C{H_4}$$ ( no lone pair of electrons ) $${109.5^ \circ }$$
$$N{H_3}$$ ( one lone pair of electrons ) $${107.5^ \circ }$$
$${H_2}O$$ ( two lone pair of electrons ) $${104.45^ \circ }$$