When temperature is changed, water is converted to ice or steam depending upon the temperature. There is no change in the chemical properties of water and only physical state changes.
112.
Lithium has a $$bcc$$ structure. Its density is $$530\,kg\,{m^{ - 3}}$$ and its atomic mass is $$6.94\,g\,mo{l^{ - 1}}.$$ Calculate the edge length of a unit cell of lithium metal.
$$\left( {{N_A} = 6.02 \times {{10}^{23}}mo{l^{ - 1}}} \right)$$
Given, $$Li$$ has a $$bcc$$ structure.
Density $$\left( \rho \right) = 530\,kg{\text{ - }}{m^{ - 3}}$$
Atomic mass $$\left( M \right) = 6.94\,g\,mo{l^{ - 1}}$$
Avogadro's number $$\left( {{N_A}} \right) = 6.02 \times {10^{23}}mo{l^{ - 1}}$$
We know that, number of atoms per unit cell in $$bcc$$ $$\left( Z \right) = 2.$$
∴ We have the formula for density,
$$\rho = \frac{{ZM}}{{{N_A}{a^3}}}$$
where $$a$$ = edge-length of a unit cell.
$$\eqalign{
& {\text{or}}\,\,a = \root 3 \of {\frac{{ZM}}{{\rho {N_A}}}} \cr
& = \root 3 \of {\frac{{2 \times 6.94\,g\,mo{l^{ - 1}}}}{{0.53\,g\,c{m^{ - 3}} \times 6.02 \times {{10}^{23}}mo{l^{ - 1}}}}} \cr
& = \root 3 \of {4.35 \times {{10}^{ - 23}}c{m^{ - 3}}} \cr
& = 3.52 \times {10^{ - 8}}cm \cr
& a = 352\,pm \cr} $$
113.
The initial volume of a gas cylinder is $$750.0$$ $$mL.$$ If
the pressure of gas inside the cylinder changes from $$840.0\,mm\,Hg$$ to $$360.0\,mm\,Hg,$$ the final volume the gas will be :
114.
For $$1$$ $$mol$$ of an ideal gas at a constant temperature
$$T,$$ the plot of $$log\,P$$ against $$log\,V$$ is a ( $$P$$ : Pressure, $$V$$ : Volume )
According to Boyle's law, $$PV=$$ constant
$$\eqalign{
& \therefore \,\,{\text{log}}\,P + {\text{log}}\,V = {\text{constant}} \cr
& \,{\text{log}}\,P = - {\text{log}}\,V + {\text{constant}} \cr} $$
Hence, the plot of $${\text{log}}\,P\,\,{\text{vs}}\,\,{\text{log}}\,V$$ is straight line with negative slope.
115.
Which of the following is not an assumption of the kinetic theory of gases?
A
Gas particles have negligible volume.
B
A gas consists of many identical particles which are in continual motion.
C
At high pressure, gas particles are difficult to compress.
D
Collisions of gas particles are perfectly elastic.
Answer :
At high pressure, gas particles are difficult to compress.
117.
A bottle of dry ammonia and a bottle of dry hydrogen chloride connected through a long tube are opened simultaneously at both ends the white ammonium chloride ring first formed will be
TIPS/Formulae :
$$\eqalign{
& {\text{Rate of diffusion}}\, \propto \,\sqrt {\frac{1}{{{\text{Molecular mass}}}}} \cr
& \because \,\,{\text{Molecular mass of }}HCl{\text{ > molecular mass of}}\,N{H_3} \cr} $$
∴ $$HCl$$ diffuses at slower rate and white ammonium chloride is first formed near $$HCl$$ bottle.
118.
The intermolecular interaction that is dependent on the inverse cube of distance between the molecules is :
Hydrogen bond is a type of strong electrostatic dipolc-dipole interaction and dependent on the inverse cube of distance between the molecular ion-dipole interaction $$ \propto \frac{1}{{{r^3}}}.$$
119.
In a flask of volume $$V$$ litres, $$0.2\,mol$$ of oxygen, $$0.4\,mol$$ of nitrogen, $$0.1\,mol$$ of ammonia and $$0.3\,mol$$ of helium are enclosed at $$27{\,^ \circ }C.$$ If the total pressure exerted by these non-reacting gases is one atmosphere, then partial pressure exerted by nitrogen is
120.
If $$NaCl$$ is doped with $${10^{ - 4}}mol\,\,\% $$ of $$SrC{l_2},$$ the concentration of cation vacancies will be $$\left( {{N_A} = 6.023 \times {{10}^{23}}mo{l^{ - 1}}} \right)$$