Average kinetic energy depends only on temperature and does not depend upon the nature of the gas.
$$\left( {\because \,K.E. = \frac{3}{2}KT} \right)$$
62.
$$50\,mL$$ of each gas $$A$$ and of gas $$B$$ takes 150 and $$200\,s$$ respectively for effusing through a pin hole under the similar conditions. If molecular mass of gas $$B$$ is 36, the molecular mass of gas $$A$$ will be
63.
Equal volumes of the gases which do not react together are confined in separate vessels. The pressure is $$200\,mm$$ and $$400\,mm$$ of $$Hg$$
respectively. If the two gases are mixed together what will be the pressure of the resulting mixture (temperature remaining constant)
When vessels are joined the volume is doubled and pressure is reduced to half \ Pressure of mixture
$$ = \frac{{200}}{2} + \frac{{400}}{2} = 300\,mm$$
64.
A bubble of air is underwater at temperature $${15^ \circ }C$$ and the pressure $$1.5\,bar.$$ If the bubble rises to the surface where the temperature is $${25^ \circ }C$$ and the pressure is $$1.0\,bar,$$ what will happen to the volume
of the bubble ?
A
Volume will become greater by a factor of 1.6.
B
Volume will become greater by a factor of 1.1.
C
Volume will become smaller by a factor of 0.70.
D
Volume will become greater by a factor of 2.5.
Answer :
Volume will become greater by a factor of 1.6.
$${P_1} = 1.5\,bar,\,{T_1} = 273 + 15 = 288\,K,$$ $${V_1} = V$$
$${P_2} = 1.0\,bar,\,{T_1} = 273 + 25 = 298K,$$ $${V_2} = ?$$
$${V_2} = 1.55\,V$$ i.e., volume of bubble will be almost 1.6 time to initial volume of bubble.
65.
$$600\,cc$$ of a gas at a pressure of $$750\,mm$$ is compressed to $$500\,cc.$$ Taking the temperature to remain constant, the increase in pressure is
66.
For one mole of a van der Waal’s gas when $$b = 0$$ and $$T = 30K,$$ the $$PV$$ vs, $$\frac{1}{V}$$ plot is shown below. The value of the van der Waal’s constant $$a\left( {atm.\,lite{r^2}mo{l^{ - 2}}} \right)$$ is:
Let initial number of moles of air at $$27{\,^ \circ }C\left( {300\,K} \right) = n$$
At temperature $$T\,K,$$ the no. of moles left $$ = n - \frac{n}{3} = \frac{{2n}}{3}$$
At constant pressure and volume, $${n_1}{T_1} = {n_2}{T_2}$$
$$\eqalign{
& n \times 300 = \frac{{2n}}{3} \times T \cr
& \Rightarrow T = 450\,K\,\,{\text{or}}\,\,177{\,^ \circ }C \cr} $$
68.
A gas occupies a volume of $$300\,c{m^3}$$ at $$27{\,^ \circ }C$$ and $$620\,mm$$ pressure. The volume of gas at $$47{\,^ \circ }C$$ and $$640\,mm$$ pressure is
70.
Pressure of $$1\,g$$ of an ideal gas $$A$$ at $${27^ \circ }C$$ is found to be $$2\,bar.$$ When $$2\,g$$ of another ideal gas $$B$$ is introduced in the same flask at same temperature the pressure becomes $$3\,bar.$$ What would be the ratio of molecular masses of $$A$$ and $$B?$$