81.
Compound $${C_2}{H_6}O$$ has two isomers $$X$$ and $$Y.$$ On reaction with $$HI, X$$ gives alkyl iodide and water while $$Y$$ gives alkyl iodide and alcohol. Compounds $$X$$ and $$Y$$ are respectively
A
$${C_2}{H_5}O{C_2}{H_5}{\text{ and }}C{H_3}O{C_2}{H_5}$$
B
$$C{H_3}OC{H_3}{\text{ and }}{C_2}{H_5}OC{H_3}$$
C
$${C_2}{H_5}OH{\text{ and }}C{H_3}OC{H_3}$$
D
$$C{H_3}OH{\text{ and }}C{H_3}OC{H_3}$$
Answer :
$${C_2}{H_5}OH{\text{ and }}C{H_3}OC{H_3}$$
$$cis$$ - cyclopenta - 1, 2 - diol when reacts with acetone, forms cyclic ketal whereas $$trans$$ - isomer of cyclopenta - 1, 2 - diol can not form cyclic ketal.
83.
Consider the following reaction,
\[\text{Phenol}\xrightarrow{Zn-\text{dust}}X\xrightarrow[\text{Anhy}\text{.}\,AlC{{l}_{3}}]{C{{H}_{3}}Cl}Y\xrightarrow{\begin{smallmatrix}
\text{Alk}\text{.} \\
KMn{{O}_{4}}
\end{smallmatrix}}Z\]
The product $$Z$$ is
86.
Sodium phenoxide when heated with $$C{O_2}$$ under pressure at
125°C yields a product which on acetylation produces $$C.$$
The major product C would be
The $$-OH$$ group of alcohol or the $$-COOH$$ group of a carboxylic acid is replaced by $$-Cl$$ using phosphorus penta chloride $$\left( {{\text{i}}{\text{.e}}{\text{.}}\,PC{l_5}} \right)$$
$$\eqalign{
& \mathop {ROH}\limits_{{\text{Alcohol}}} + PC{l_5} \to RCl + POC{l_3} + HCl \cr
& \mathop {RCOOH}\limits_{{\text{Acid}}} + PC{l_5} \to RCOCl + POC{l_3} + HCl \cr} $$
Resonance stabilisation of phenoxide ion
\[{{C}_{2}}{{H}_{5}}-\underset{\text{Stable}}{\mathop{O}}\,-H\rightleftharpoons \underset{\begin{smallmatrix}
\text{ Unstable} \\
\text{ ethoxide ion}
\\
\text{(due to absence of resonance)}
\end{smallmatrix}}{\mathop{{{C}_{2}}{{H}_{5}}-{{O}^{-}}+{{H}^{+}}}}\,\]
Phenoxide ion is more stable than ethoxide ion due to resonance. Therefore, the ionisation constant of phenol is higher than ethanol.
90.
For the identification of $$\beta $$ - naphthol using dye test, it is necessary to use
A
Dichloromethane solution of $$\beta $$ - naphthol
B
Acidic solution of $$\beta $$ - naphthol
C
Neutral solution of $$\beta $$ - naphthol
D
Alkaline solution of $$\beta $$ - naphthol
Answer :
Alkaline solution of $$\beta $$ - naphthol