31.
In the following sequence of reaction, identify the compounds $$(A), (B), (C)$$ and $$(D) :$$
\[\underset{\text{Solution}}{\mathop{N{{a}_{2}}C{{O}_{3}}}}\,\xrightarrow{S{{O}_{2}}}\left( A \right)\xrightarrow{N{{a}_{2}}C{{O}_{3}}}\] \[\left( B \right)\xrightarrow[\text{Heat}]{S}\left( C \right)\xrightarrow{AgN{{O}_{3}}}\left( D \right)\]
A
$$N{a_2}S{O_3},NaHS{O_3},N{a_2}S,A{g_2}S$$
B
$$NaHS{O_3},N{a_2}S{O_3},N{a_2}{S_2}{O_3},A{g_2}S$$
C
$$NaHS{O_3},N{a_2}S{O_4},N{a_2}S,A{g_2}O$$
D
$$N{a_2}S{O_3},N{a_2}S{O_4},N{a_2}{S_2}{O_3},Ag$$
\[\begin{align}
& N{{a}_{2}}C{{O}_{3}}+2S{{O}_{2}}+{{H}_{2}}O\to \underset{\left( A \right)}{\mathop{2NaHS{{O}_{3}}}}\,+C{{O}_{2}} \\
& \underset{\left( A \right)}{\mathop{2NaHS{{O}_{3}}}}\,+N{{a}_{2}}C{{O}_{3}}\to \underset{\left( B \right)}{\mathop{2N{{a}_{2}}S{{O}_{3}}}}\,+{{H}_{2}}O+C{{O}_{2}} \\
& \underset{\left( B \right)}{\mathop{2N{{a}_{2}}S{{O}_{3}}}}\,+S\xrightarrow{\text{Heat}}\underset{\left( C \right)}{\mathop{2N{{a}_{2}}{{S}_{2}}{{O}_{3}}}}\, \\
& N{{a}_{2}}{{S}_{2}}{{O}_{3}}+AgN{{O}_{3}}\to \underset{\left( D \right)}{\mathop{A{{g}_{2}}S}}\,+{{H}_{2}}S{{O}_{4}} \\
\end{align}\]
32.
The set representing the correct order of first ionization potential is
$$ \bullet \,\,C{a^{2 + }}\,ions$$ are very important factor in blood clotting.
$$ \bullet \,\,C{a^{2 + }}\,ions$$ are very important for maintaining the regular heart beating.
$$ \bullet\, \,M{g^{2 + }}\,ions$$ is present in the green parts of plants i.e., chlorophyll.
$$ \bullet \,\,M{g^{2 + }}$$ can form a complex with $$ATP.$$
Bleaching powder is prepared by passing chlorine gas over dry slaked lime $$Ca{\left( {OH} \right)_2}$$ by Hesenclaver method or by Bachmann method.
$$Ca{\left( {OH} \right)_2} + C{l_2} \to CaOC{l_2} + {H_2}O$$
38.
Which one of the following is present as an active ingredient in bleaching powder for
bleaching action ?