481. Trigonal bipyramidal geometry is shown by :

A $$Xe{O_3}$$
B $$Xe{O_3}{F_2}$$
C $$FXeOS{O_2}F$$
D $${\left[ {Xe{F_8}} \right]^{2 - }}$$
Answer :   $$Xe{O_3}{F_2}$$
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482. Which one of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at $${90^ \circ }C?$$

A $$C{l_2}O$$
B $$Cl{O_3}$$
C $$Cl{O_2}$$
D $$Cl{O_4}$$
Answer :   $$Cl{O_2}$$
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483. Which of the following statements is not valid for oxoacids of phosphorus?

A Orthophosphoric acid is used in the manufacture of triple superphosphate
B Hypophosphorous acid is a diprotic acid
C All oxoacids contain tetrahedral four coordinated phosphorus
D All oxoacids contain at least one $$P =O$$  unit and one $$P—OH$$  group
Answer :   Hypophosphorous acid is a diprotic acid
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484. Boric acid is the trival name for

A orthoboric acid
B metaboric acid
C pyroboric acid
D none of these
Answer :   orthoboric acid
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485. The shape of $$Xe{O_2}{F_2}$$  molecule is

A trigonal bipyramidal
B square planar
C tetrahedral
D see-saw
Answer :   see-saw
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486. Which one of the following orders is correct for the bond dissociation enthalpy of halogen molecules?

A $$C{l_2} > B{r_2} > {F_2} > {I_2}$$
B $$B{r_2} > {I_2} > {F_2} > C{l_2}$$
C $${F_2} > C{l_2} > B{r_2} > {I_2}$$
D $${I_2} > B{r_2} > C{l_2} > {F_2}$$
Answer :   $$C{l_2} > B{r_2} > {F_2} > {I_2}$$
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487. Anhydrous $$AlC{l_3}$$  cannot be obtained from which of the following reactions ?

A Heating $$AlC{l_3}.6{H_2}O$$
B By passing dry $$HCl$$  over hot aluminium powder
C By passing dry $$C{l_2}$$  over hot aluminium powder
D By passing dry $$C{l_2}$$  over a hot mixture of alumina and coke
Answer :   Heating $$AlC{l_3}.6{H_2}O$$
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488. Blue liquid which is obtained on reacting equimolar amounts of two gases at $${30^ \circ }C$$  is?

A $${N_2}O\,$$
B $${N_2}{O_3}\,$$
C $${N_2}{O_4}$$
D $${N_2}{O_5}\,$$
Answer :   $${N_2}{O_3}\,$$
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489. Dry $$S{O_2}$$  does not bleach dry flowers because

A nascent hydrogen responsible for bleaching is produced only in presence of moisture
B water is the actual reducing agent responsible for bleaching
C water is stronger acid than $$S{O_2}$$
D the $$O{H^ - }$$  ions produced by water cause bleaching
Answer :   nascent hydrogen responsible for bleaching is produced only in presence of moisture
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490. Anhydrous $$AlC{l_3}$$  is prepared from

A $$conc.\,HCl$$   and $$Al$$  metal
B aluminium and $$C{l_2}$$
C dry $$HCl$$  gas + heated $$Al$$  metal
D $$dil.HCl$$   and $$Al$$  metal
Answer :   dry $$HCl$$  gas + heated $$Al$$  metal
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