The hybridization of $$Xe{O_3}{F_2}$$ is $$s{p^3}d$$ and its structure is trigonal bipyramidal in which oxygen atoms are situated on the plane and the fluoride atoms are on the top and bottom.
482.
Which one of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at $${90^ \circ }C?$$
Pure $$Cl{O_2}$$ is obtained by passing dry $$C{l_2}$$ over $$AgCl{O_3}$$ at $${90^ \circ }C.$$
\[2AgCl{{O}_{3}}+C{{l}_{2}}\left( \text{dry} \right)\xrightarrow{{{90}^{\circ }}C}\] \[2AgCl+2Cl{{O}_{2}}+{{O}_{2}}\]
483.
Which of the following statements is not valid for oxoacids of phosphorus?
A
Orthophosphoric acid is used in the manufacture of triple superphosphate
B
Hypophosphorous acid is a diprotic acid
C
All oxoacids contain tetrahedral four coordinated phosphorus
D
All oxoacids contain at least one $$P =O$$ unit and one $$P—OH$$ group
Hypophosphorous acid, $${H_3}P{O_2},$$ has the following structure.
As it contains only one replaceable $$H$$-atom ( that is attached with $$O,$$ not with $$P$$ directly ) so it is a monoprotic acid.
All other given statements are true.
As the size increases, bond dissociation enthalpy becomes lower. Also, as the size of atoms get smaller, ion pairs on the two atoms get close enough together to experience repulsion. In case of $${F_2},$$ this repulsion is bigger and bond becomes weaker.
Hence, the correct order is $$C{l_2} > B{r_2} > {F_2} > {I_2}.$$
487.
Anhydrous $$AlC{l_3}$$ cannot be obtained from which of the following reactions ?
A
Heating $$AlC{l_3}.6{H_2}O$$
B
By passing dry $$HCl$$ over hot aluminium powder
C
By passing dry $$C{l_2}$$ over hot aluminium powder
D
By passing dry $$C{l_2}$$ over a hot mixture of alumina and coke
\[NO\left( g \right)+N{{O}_{2}}\left( g \right)\xrightarrow{-{{30}^{\circ }}C}\underset{\left( \text{blue}\,\,\text{liquid} \right)}{\mathop{{{N}_{2}}{{O}_{3}}}}\,\]
489.
Dry $$S{O_2}$$ does not bleach dry flowers because
A
nascent hydrogen responsible for bleaching is produced only in presence of moisture
B
water is the actual reducing agent responsible for bleaching
C
water is stronger acid than $$S{O_2}$$
D
the $$O{H^ - }$$ ions produced by water cause bleaching
Answer :
nascent hydrogen responsible for bleaching is produced only in presence of moisture