461.
Ammonia can be dried by
A
$${\text{conc}}{\text{.}}\,{H_2}S{O_4}$$
B
$${P_4}{O_{10}}$$
C
$$CaO$$
D
$${\text{anhydrous}}\,CaC{l_2}$$
Answer :
$$CaO$$
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$$N{H_3}$$ does not react with $$CaO$$ while other reacts with
$$N{H_3}$$
$$\eqalign{
& 2N{H_3} + {H_2}S{O_4} \to {\left( {N{H_4}} \right)_2}S{O_4} \cr
& {P_4}{O_{10}} + 12N{H_3} \to 4{\left( {N{H_4}} \right)_3}P{O_4} + 6{H_2}O \cr
& CaC{l_2} + 8{H_2}O \to CaC{l_2}.8{H_2}O \cr} $$
462.
Which one of the following oxides is expected to exhibit paramagnetic behaviour?
A
$$C{O_2}$$
B
$$S{O_2}$$
C
$$Cl{O_2}$$
D
$$Si{O_2}$$
Answer :
$$Cl{O_2}$$
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$$Cl{O_2}$$ shows paramagnetic character due to presence of unpaired electron in its structure.
463.
A deep brown gas is formed by mixing two colourless gases which are
A
$$N{O_2}\,\,{\text{and}}\,\,{O_2}$$
B
$${N_2}O\,\,{\text{and}}\,\,NO$$
C
$$NO\,\,{\text{and}}\,\,{O_2}$$
D
$$N{H_3}\,\,{\text{and}}\,\,HCl$$
Answer :
$$NO\,\,{\text{and}}\,\,{O_2}$$
464.
Dry ice is
A
$${\text{solid}}\,N{H_3}$$
B
$${\text{solid}}\,S{O_2}$$
C
$${\text{solid}}\,C{O_2}$$
D
$${\text{solid}}\,{N_2}$$
Answer :
$${\text{solid}}\,C{O_2}$$
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No explanation is given for this question. Let's discuss the answer together.
465.
Brown colour in $$HN{O_3}$$ can be removed by
A
adding $$Mg$$ powder.
B
boiling the acid.
C
passing $$N{H_3}$$ through acid.
D
passing air through warm acid.
Answer :
passing air through warm acid.
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Nitric acid decomposes to give $$N{O_2}$$ which is brown
$$4HN{O_3} \to 4N{O_2} + 2{H_2}O + {O_2}$$
When air is passed through acid the reaction proceeds towards left hand side and brown colour diminishes.
466.
Lead pipes are not suitable for drinking water because
A
lead forms basic lead carbonate
B
lead reacts with water containing air to form $$Pb{\left( {OH} \right)_2}$$
C
a layer of lead dioxide is deposited over pipes
D
lead reacts with air to form litharge
Answer :
lead reacts with water containing air to form $$Pb{\left( {OH} \right)_2}$$
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$$2Pb + 2{H_2}O + {O_2} \to 2Pb{\left( {OH} \right)_2}$$
467.
Excess of $$KI$$ reacts with $$CuS{O_4}$$ solution and then $$N{a_2}{S_2}{O_3}$$ solution is added to it. Which of the statements is incorrect for this reaction ?
A
$$N{a_2}{S_2}{O_3}$$ is oxidised
B
$$Cu{I_2}$$ is formed
C
$$C{u_2}{I_2}$$ is formed
D
Evolved $${I_2}$$ is reduced
Answer :
$$Cu{I_2}$$ is formed
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$$\eqalign{
& 4\mathop {KI}\limits^{ - 1} + 2CuS{O_4} \to \mathop {{I_2}}\limits^0 + C{u_2}{I_2} + 2{K_2}S{O_4} \cr
& \mathop {{I_2}}\limits^0 + \mathop {2N{a_2}{S_2}{O_3}}\limits^{2 + } \to \mathop {N{a_2}{S_4}{O_6}}\limits^{ - 2.5} + 2N\mathop {aI}\limits^{ - 1} \cr
& {\text{In this}}\,Cu{I_2}\,{\text{is not formed}}{\text{.}} \cr} $$
468.
Choose the correct statements from the following.
A
Rhombic sulphur is blue in colour.
B
Rhombic sulphur is soluble in water but insoluble in organic solvents.
C
Rhombic and monoclinic sulphur have $${S_6}$$ molecules.
D
In cycle - $${S_6}$$ molecule, the ring adopts chair form.
Answer :
In cycle - $${S_6}$$ molecule, the ring adopts chair form.
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No explanation is given for this question. Let's discuss the answer together.
469.
Which of the following is not a use of noble gases?
A
Argon is widely used for filling incandescent electric bulbs.
B
Neon is used in safety devices for protecting electrical instruments.
C
Radon is used in radiotherapy of cancer.
D
Helium is filled in tubes of cycles and scooters tyres.
Answer :
Helium is filled in tubes of cycles and scooters tyres.
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Helium is used in filling tubes of aeroplane tyres.
470.
Nitrogen is relatively inactive element because
A
its atoms has a stable electronic configuration
B
it has low atomic radius
C
its electronegativity is fairly high
D
dissociation energy of its molecule is fairly high
Answer :
dissociation energy of its molecule is fairly high
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$${N_2}$$ molecule contains triple bond between $$N$$ atoms, having very high dissociation energy $$\left( {946\,kJ\,mo{l^{ - 1}}} \right)$$ due to which it is relatively inactive.