121. Which of the following hydroxide is acidic ?

A $$Al{\left( {OH} \right)_3}$$
B $$Ca{\left( {OH} \right)_3}$$
C $$Tl{\left( {OH} \right)_3}$$
D $$B{\left( {OH} \right)_3}$$
Answer :   $$B{\left( {OH} \right)_3}$$
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122. $$HCl$$  can be prepared by

A \[NaCl+{{H}_{2}}S{{O}_{4}}\xrightarrow{420\,K}\]
B \[NaHS{{O}_{4}}+NaCl\xrightarrow{823\,K}\]
C \[NaN{{O}_{3}}+{{H}_{2}}S{{O}_{4}}\to \]
D \[\text{both (A) and (B)}\]
Answer :   \[\text{both (A) and (B)}\]
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123. How can the following reaction be made to proceed in forward direction?
$$B{\left( {OH} \right)_3} + NaOH \rightleftharpoons NaB{O_2} + Na\left[ {B{{\left( {OH} \right)}_4}} \right] + {H_2}O$$

A addition of borax
B addition of $$cis{\text{ - 1, 2 - diol }}$$
C addition of $$N{a_2}HP{O_4}$$
D addition of $$trans{\text{ - 1, 2 - diol }}$$
Answer :   addition of $$cis{\text{ - 1, 2 - diol }}$$
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124. Name of the synthetic radioactive element of group 16 having atomic number 116 is

A Livermorium
B Tennessine
C Livernorium
D Moscovium.
Answer :   Livermorium
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125. Which of the following statements is not correct?

A Oxygen molecule is paramagnetic with two unpaired electrons.
B Sulphur shows maximum covalency of four.
C Ozone can be easily detected by mercury.
D Both sulphurous and sulphuric acid are dibasic in nature.
Answer :   Sulphur shows maximum covalency of four.
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126. Which of the following halides is least stable and has doubtful existence?

A $$C{l_4}$$
B $$Ge{I_4}$$
C $$Sn{I_4}$$
D $$Pb{I_4}$$
Answer :   $$Pb{I_4}$$
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127. The reason for not storing $$Xe{F_6}$$  in a glass or a quartz vessel is that

A it forms an explosive having the formula $$Xe{O_2}{F_2}.$$
B it forms an explosive having the formula $$XeO{F_4}.$$
C it forms $$Xe{O_2}$$  which is explosive substance.
D it forms $$Xe{O_6}^{4 - }$$  which is explosive in nature.
Answer :   it forms an explosive having the formula $$XeO{F_4}.$$
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128. An aqueous solution of $$FeS{O_4},A{l_2}{\left( {S{O_4}} \right)_3}$$     and chrome alum is heated with excess of $$N{a_2}{O_2}$$  and filtered. The materials obtained are :

A a colourless filtrate and a green residue
B a yellow filtrate and a green residue
C a yellow filtrate and a brown residue
D a green filtrate and a brown residue
Answer :   a yellow filtrate and a brown residue
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129. Which reaction represents the oxidizing behaviour of $${H_2}S{O_4}?$$

A $$2PC{l_5} + {H_2}S{O_4} \to $$     $$2POC{l_3} + 2HCl + S{O_2}C{l_2}$$
B $$2NaOH + {H_2}S{O_4} \to $$     $$N{a_2}S{O_4} + 2{H_2}O$$
C $$NaCl + {H_2}S{O_4} \to NaHS{O_4} + HCl$$
D $$2HI + {H_2}S{O_4} \to {I_2} + S{O_2} + 2{H_2}O$$
Answer :   $$2HI + {H_2}S{O_4} \to {I_2} + S{O_2} + 2{H_2}O$$
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130. Which of the following statements about $${H_3}B{O_3}$$  is not correct?

A It is a strong tribasic acid
B It is prepared by acidifying an aqueous solution of borax
C It has a layer structure in which planar $$B{O_3}$$  units are joined by hydrogen bonds
D It does not act as proton donor but acts as a Lewis acid by accepting hydroxyl ion
Answer :   It is a strong tribasic acid
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