Question

Which one of the following undergoes reaction with 50% sodium hyroxide solution to give the corresponding alcohol and acid?

A. Butanal
B. Benzaldehyde  
C. Phenol
D. Benzoic acid
Answer :   Benzaldehyde
Solution :
This reaction is known as cannizzaro’s reaction. In this reaction benzaldehyde in presence of 50%. $$NaOH$$  undergoes disproportionation reaction and form one mol of Benzyl alcohol (Red. product) and one mole of sod. benzoate (ox. product)
Aldehyde and Ketone mcq solution image

Releted MCQ Question on
Organic Chemistry >> Aldehyde and Ketone

Releted Question 1

The reagent with which both acetaldehyde and acetone react easily is

A. Fehling’s reagent
B. Grignard reagent
C. Schiff’s reagent
D. Tollen’s reagent
Releted Question 2

The Cannizzaro reaction is not given by

A. trimethylacetaldehye
B. acetaldehyde
C. benzaldehyde
D. formaldehyde
Releted Question 3

The compound that will not give iodoform on treatment with alkali and iodine is :

A. acetone
B. ethanol
C. diethyl ketone
D. isopropyl alcohol
Releted Question 4

Polarisation of electrons in acrolein may be written as

A. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - \mathop {CH}\limits^{{\delta ^ + }} = O$$
B. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - CH = \mathop O\limits^{{\delta ^ + }} $$
C. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = \mathop {CH}\limits^{{\delta ^ + }} - CH = O$$
D. $$\mathop {C{H_2}}\limits^{{\delta ^ + }} = CH - CH = \mathop O\limits^{{\delta ^ - }} $$

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Aldehyde and Ketone


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