Question

Which one is not paramagnetic among the following ? [ at. no. of $$Be = 4,\,Ne = 10,\,As = 33,\,Cl = 17\,$$       ]

A. $$C{l^ - }$$  
B. $$Be$$
C. $$N{e^{2 + }}$$
D. $$A{s^ + }$$
Answer :   $$C{l^ - }$$
Solution :
Paramagnetic character is based upon presence of unpaired electron.
$${}_{17}C{l^ - } = 1{s^2},2{s^2}2{p^6},3{s^2}3p_x^23p_y^23p_z^2$$
In $$C{l^ - }$$ no unpaired electron, so it is in nature diamagnetic.
$${}_4Be = 1{s^2},2{s^1}2p_x^1$$
$${}_{10}N{e^{2 + }} = 1{s^2},2{s^2}2p_x^22p_y^12p_z^1$$
$${}_{33}A{s^ + } = 1{s^2},2{s^2}2{p^6},3{s^2}3{p^6}3{d^{10}},$$       $$4{s^2}4p_x^14p_y^14p_z^0$$
While all others have unpaired electron, so they are paramagnetic in nature.

Releted MCQ Question on
Inorganic Chemistry >> Chemical Bonding and Molecular Structure

Releted Question 1

The compound which contains both ionic and covalent bonds is

A. $$C{H_4}$$
B. $${H_2}$$
C. $$KCN$$
D. $$KCl$$
Releted Question 2

The octet rule is not valid for the molecule

A. $$C{O_2}$$
B. $${H_2}O$$
C. $${O_2}$$
D. $$CO$$
Releted Question 3

Element $$X$$ is strongly electropositive and element $$Y$$ is strongly electronegative. Both are univalent. The compound formed would be

A. $${X^ + }{Y^ - }$$
B. $${X^ - }{Y^{ + \,}}$$
C. $$X - Y$$
D. $$X \to Y$$
Releted Question 4

Which of the following compounds are covalent?

A. $${H_2}$$
B. $$CaO$$
C. $$KCl$$
D. $$N{a_2}S$$

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Chemical Bonding and Molecular Structure


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