Question

Which of the following statements is not correct about $${S_N}2$$  reactions of alkyl halides?

A. Nucleophile attacks the carbon from the side opposite to where the leaving group is attached.
B. The bond formation and bond breaking take place in one step.
C. The rate of reaction depends upon the concentration of nucleophile.
D. $${S_N}2$$  mechanism is predominant in tertiary alkyl halides.  
Answer :   $${S_N}2$$  mechanism is predominant in tertiary alkyl halides.

Releted MCQ Question on
Organic Chemistry >> Electrophilic Aromatic Substitution (Haloalkanes and Haloarenes)

Releted Question 1

The reaction of toluene with chlorine in presence of ferric chloride gives predominantly :

A. benzoyl chloride
B. $$m $$ - chlorotoluene
C. benzyl chloride
D. $$o $$ - and $$p $$ - chlorotoluene
Releted Question 2

Bottles containing $${C_6}{H_5}I$$  and $${C_6}{H_5}C{H_2}I$$   lost their original labels. They were labelled $$A$$ and $$B$$ for testing. $$A$$ and $$B$$ were separately taken in test tubes and boiled with $$NaOH$$  solution. The end solution in each tube was made acidic with dilute $$HN{O_3}$$  and then some $$AgN{O_3}$$  solution was added. Substance B gave a yellow precipitate. Which one of the following statements is true for this experiment ?

A. $$A$$ and $${C_6}{H_5}C{H_2}I$$
B. $$B$$ and $${C_6}{H_5}I$$
C. Addition of $$HN{O_3}$$  was unnecessary
D. $$A$$ was $${C_6}{H_5}I$$
Releted Question 3

Fluorobenzene $$\left( {{C_6}{H_5}F} \right)$$  can be synthesized in the laboratory

A. by direct fluorination of benzene with $${F_2}$$  gas
B. by reacting bromobenzene with $$NaF$$  solution
C. by heating phenol with $$HF$$  and $$KF$$
D. from aniline by diazotisation followed by heating the diazonium salt with $$HB{F_4}$$
Releted Question 4

Reaction of $$trans$$  2 - phenyl - 1 - bromocyclopentane on reaction with alcoholic $$KOH$$  produces

A. 1 - phenylcyclopentene
B. 3 - phenylcyclopentene
C. 4 - phenylcyclopentene
D. 2 - phenylcyclopentene

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