Question
Which of the following reactions will not result in the formation of anisole ?
A.
Phenol + dimethyl sulphate in presence of a base
B.
Sodium phenoxide is treated with methyl iodide
C.
Reaction of diazomethane with phenol
D.
Reaction of methylmagnesium iodide with phenol
Answer :
Reaction of methylmagnesium iodide with phenol
Solution :
Phenol has active (acidic) hydrogen so it reacts with $$C{H_3}MgI$$ to give $$C{H_4},$$ and not anisole $${C_6}{H_5}OH + C{H_3}MgI \to $$ $$C{H_4} + {C_6}{H_5}OMgI$$