Question

Which of the following is most powerful to coagulate the negative colloid?

A. $$ZnS{O_4}$$
B. $$N{a_3}P{O_4}$$
C. $$AlC{l_3}$$  
D. $${K_4}\left[ {Fe{{\left( {CN} \right)}_6}} \right]$$
Answer :   $$AlC{l_3}$$
Solution :
According to Hardy-Schulze rule "The amount of electrolyte required to coagulate a fixed amount of a sol depends upon the sign of charge and valency of the flocculating ion."
Thus, the coagulating power vary in the order.
$$A{l^{3 + }} > Z{n^{2 + }} > N{a^ + }$$

Releted MCQ Question on
Physical Chemistry >> Surface Chemistry

Releted Question 1

Rate of physiorption increases with

A. decrease in temperature
B. increase in temperature
C. decrease in pressure
D. decrease in surface area
Releted Question 2

Adsorption of gases on solid surface is generally exothermic because

A. enthalpy is positive
B. entropy decreases
C. entropy increases
D. free energy increases
Releted Question 3

Lyophilic sols are

A. Irreversible sols
B. They are prepared from inorganic compound
C. Coagulated by adding electrolytes
D. Self-stabilizing
Releted Question 4

Among the following, the surfactant that will form micelles in aqueous solution at the lowest molar concentration at ambient condition is : -

A. $$C{H_3}{\left( {C{H_2}} \right)_{15}}{N^ + }{\left( {C{H_3}} \right)_3}B{r^ - }$$
B. $$C{H_3}{\left( {C{H_2}} \right)_{11}}OSO_3^ - N{a^ + }$$
C. $$C{H_3}{\left( {C{H_2}} \right)_6}CO{O^ - }N{a^ + }$$
D. $$C{H_3}{\left( {C{H_2}} \right)_{11}}{N^ + }{\left( {C{H_3}} \right)_3}B{r^ - }$$

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