Question

Which has most stable $$ + 2$$  oxidation state :

A. $$Sn$$
B. $$Pb$$  
C. $$Fe\,$$
D. $$Ag$$
Answer :   $$Pb$$
Solution :
TIPS/Formulae :
(i) Ion having half filled or full filled orbital have extra stability.
(ii) Larger the size of cation more will be its stability $$P{b^{2 + }}\left( {5{d^{10}}6{s^2}} \right),$$    has the most stable $$ + 2$$  oxidation state because here the $$d$$-orbital is completely filled and is more stable than $$F{e^{2 + }}\left( {3{d^6}} \right).$$   Again $$A{g^ + }\left( {4{d^{10}}} \right)$$   is more stable as here again the $$d$$-orbital is completely filled and $$A{g^{2 + }}$$  is not easily obtained. $$P{b^{2 + }}$$  is more stable compared to $$S{n^{2 + }}\left( {4{d^{10}}5{s^2}} \right)$$    because of its large size.

Releted MCQ Question on
Inorganic Chemistry >> Classification of Elements and Periodicity in Properties

Releted Question 1

The correct order of second ionisation potential of carbon, nitrogen, oxygen and fluorine is

A. $$C > N > O > F$$
B. $$O > N > F > C$$
C. $$O > F > N > C$$
D. $$F > O > N > C$$
Releted Question 2

The element with the highest first ionization potential is

A. boron
B. carbon
C. nitrogen
D. oxygen
Releted Question 3

The first ionisation potential in electron volts of nitrogen and oxygen atoms are respectively given by

A. $$14.6,13.6\,$$
B. $$13.6,14.6$$
C. $$13.6,13.6$$
D. $$14.6,14.6$$
Releted Question 4

Atomic radii of fluorine and neon in $$\mathop {\text{A}}\limits^ \circ $$ngstorm units are respectively given by

A. $$0.72,1.60$$
B. $$1.60,1.60\,$$
C. $$0.72,0.72\,\,$$
D. None of these values

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Classification of Elements and Periodicity in Properties


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