Question

When equal volumes of the following solutions are mixed, precipitation of $$AgCl\left( {{K_{sp}} = 1.8 \times {{10}^{ - 10}}} \right)$$     will occur only with

A. $${10^{ - 4}}M\left( {A{g^ + }} \right)\,{\text{and}}\,{10^{ - 4}}M\left( {C{l^ - }} \right)$$  
B. $${10^{ - 5}}M\left( {A{g^ + }} \right)\,{\text{and}}\,{10^{ - 5}}M\left( {C{l^ - }} \right)$$
C. $${10^{ - 6}}M\left( {A{g^ + }} \right)\,{\text{and}}\,{10^{ - 6}}M\left( {C{l^ - }} \right)$$
D. $${10^{ - 10}}M\left( {A{g^ + }} \right)\,{\text{and}}\,{10^{ - 10}}M\left( {C{l^ - }} \right)$$
Answer :   $${10^{ - 4}}M\left( {A{g^ + }} \right)\,{\text{and}}\,{10^{ - 4}}M\left( {C{l^ - }} \right)$$
Solution :
For a precipitation to occur Solubility product < Ionic product Given K sp =1.8× 10 10 Calculating ionic products in each Ionicproduct= A g + C l = 10 4 2 × 10 4 2 =2.5× 10 9 which is greater than K sp 1.8× 10 10 . equal volumes are mixed, so A g + = 10 4 2 and C l = 10 4 2 step2

Releted MCQ Question on
Physical Chemistry >> Ionic Equilibrium

Releted Question 1

Molten sodium chloride conducts electricitry due to the presence of

A. free electrons
B. free ions
C. free molecules
D. atoms of sodium and chlorine
Releted Question 2

An acidic buffer solution can be prepared by mixing the solutions of

A. ammonium acetate and acetic acid
B. ammonium chloride and ammonioum hydroxide
C. sulphuric acid and sodium sulphate
D. sodium chloride and sodium hydroxide.
Releted Question 3

The $$pH$$ of a 10-8 molar solution of $$HCl$$  in water is

A. 8
B. -8
C. between 7 and 8
D. between 6 and 7
Releted Question 4

Of the given anions, the strongest Bronsted base is

A. $$CI{O^ - }$$
B. $$CIO_2^ - $$
C. $$CIO_3^ - $$
D. $$CIO_4^ - $$

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Ionic Equilibrium


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