Question

When an oxide of manganese $$(P)$$  is fused with $$KOH$$  in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound $$(Q).$$  Compound $$(Q)$$  disproportionates in neutral or acidic solution to give purple compound $$(R).$$  An alkaline solution of compound $$(R)$$  oxidises potassium iodide solution to a compound $$(S)$$  and compound $$(P)$$  is also formed. Compounds $$P$$  to $$S$$  are
$$P$$ $$Q$$ $$R$$ $$S$$
(a) $$MnO_4^ - $$ $$KI{O_3}$$ $$Mn{O_2}$$ $${K_2}Mn{O_4}$$
(b) $$Mn{O_2}$$ $${K_2}Mn{O_4}$$ $$MnO_4^ - $$ $$KI{O_3}$$
(c) $$Mn{O_2}$$ $$MnO_4^ - $$ $${K_2}Mn{O_4}$$ $$KI{O_3}$$
(d) $${K_2}Mn{O_4}$$ $$Mn{O_2}$$ $$MnO_4^ - $$ $$KI{O_3}$$

A. (a)
B. (b)  
C. (c)
D. (d)
Answer :   (b)
Solution :
$$P = Mn{O_2},Q = {K_2}Mn{O_4},$$      $$R = KMn{O_4},S = KI{O_3}$$
$$\mathop {2Mn{O_2}}\limits_{\left( P \right)} + 4KOH + {O_2} \to $$      $$\mathop {2{K_2}Mn{O_4}}\limits_{\left( Q \right)} + 2{H_2}O$$
$$3MnO_4^{2 - } + 4{H^ + } \to $$     $$\mathop {2MnO_4^ - }\limits_{\left( R \right)} + Mn{O_2} + 2{H_2}O$$
$$2MnO_4^ - + {H_2}O + KI \to $$      $$\mathop {2Mn{O_2}}\limits_{\left( P \right)} + 2O{H^ - } + \mathop {KI{O_3}}\limits_{\left( S \right)} $$

Releted MCQ Question on
Inorganic Chemistry >> D and F Block Elements

Releted Question 1

When same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide, the ratio of volume of hydrogen evolved is

A. $$1:1$$
B. $$1:2$$
C. $$2:1$$
D. $$9:4$$
Releted Question 2

Which of the following is the weakest base

A. $$NaOH$$
B. $$Ca{\left( {OH} \right)_2}$$
C. $$KOH$$
D. $$Zn{\left( {OH} \right)_2}$$
Releted Question 3

One of the constituent of German silver is

A. $$Ag$$
B. $$Cu$$
C. $$Mg$$
D. $$Al$$
Releted Question 4

Which of the following dissolve in hot conc.$$NaOH$$  solution

A. $$Fe$$
B. $$Zn$$
C. $$Cu$$
D. $$Ag$$

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D and F Block Elements


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