Question

The velocity of particle $$A$$ is $$0.1\,m{s^{ - 1}}$$  and that of particle $$B$$ is $$0.05\,m{s^{ - 1}}.$$  If the mass of particle $$B$$ is five times that of particle $$A,$$ then the ratio of de-Broglie wavelengths associated with the particles $$A$$ and $$B$$ is

A. 2 : 5
B. 3 : 4
C. 6 : 4
D. 5 : 2  
Answer :   5 : 2
Solution :
$${\text{Given,}}\,{v_A} = 0.1\,m{s^{ - 1}}\,{\text{and}}$$      $${v_B} = 0.05\,m{s^{ - 1}}{\text{also,}}$$     $${m_B} = 5{m_A}$$
$$\eqalign{ & {\text{de - Broglie wavelength,}}\,\lambda = \frac{h}{{mv}} \cr & \therefore \,\,\frac{{{\lambda _A}}}{{{\lambda _B}}} = \frac{{\frac{h}{{{m_A}{v_A}}}}}{{\frac{h}{{{m_B}{v_B}}}}} = \frac{{{m_B}{v_B}}}{{{m_A}{v_A}}} \cr & = \frac{{5{m_A} \times 0.05}}{{{m_A} \times 0.1}} = 5 \times 0.5 = 2.5 = \frac{5}{2} \cr & \therefore \,\,{\lambda _A}:{\lambda _B} = 5:2 \cr} $$

Releted MCQ Question on
Physical Chemistry >> Atomic Structure

Releted Question 1

The number of neutrons in dipositive zinc ion with mass number 70 is

A. 34
B. 36
C. 38
D. 40
Releted Question 2

Rutherford’s experiment on scattering of $$a$$ -particles showed for the first time that the atom has

A. electrons
B. protons
C. nucleus
D. neutrons
Releted Question 3

Any $$p-$$orbital can accommodate upto

A. four electrons
B. six electrons
C. two electrons with parallel spins
D. two electrons with opposite spins
Releted Question 4

The principal quantum number of an atom is related to the

A. size of the orbital
B. spin angular momentum
C. orbital angular momentum
D. orientation of the orbital in space

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