Question
The reaction $$X \to Y$$ is an exothermic reaction. Activation energy of the reaction for $$X$$ into $$Y$$ is $$150\,kJ\,mo{l^{ - 1}}.$$ Enthalpy of reaction is $$135\,kJ\,mo{l^{ - 1}}.$$ The activation energy for the reverse reaction, $$Y \to X$$ will be :
A.
$$280\,kJ\,mo{l^{ - 1}}$$
B.
$$285\,kJ\,mo{l^{ - 1}}$$
C.
$$270\,kJ\,mo{l^{ - 1}}$$
D.
$$15{\kern 1pt} \,kJ\,mo{l^{ - 1}}$$
Answer :
$$285\,kJ\,mo{l^{ - 1}}$$
Solution :
$$\eqalign{
& X \to Y;\Delta H = - 135\,kJ/mol, \cr
& {E_a} = 150\,kJ/mol \cr
& {\text{For an exothermic reaction}} \cr
& {E_{a\left( {F.R} \right)}} = \Delta H + E{'_{a\left( {B.R.} \right)}} \cr
& 150 = - 135 + E{'_{a\left( {B.R.} \right)}} \cr
& E{'_{a\left( {B.R.} \right)}} = 285\,kJ/mol \cr} $$