Question

The half-life for radioactive decay of $$C-14$$  is 5730 years. An archaeological artifact containing wood had only $$80\% $$  of the $$C-14$$  found in a living tree. The age of the sample is

A. 1485 years
B. 1845 years  
C. 530 years
D. 4767 years
Answer :   1845 years
Solution :
Radioactive decay follows first order kinetics.
$$\eqalign{ & {\text{Therefore,}} \cr & {\text{Decay constant}}\left( \lambda \right) = \frac{{0.693}}{{{t_{\frac{1}{2}}}}} \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = \frac{{0.693}}{{5730}} \cr & {\text{Given,}}\left[ {{R_0}} \right] = 100 \cr & \therefore \,\,\left[ R \right] = 80 \cr & {\text{and}}\,\,t = \frac{{2.303}}{\lambda }\log \frac{{{{\left[ R \right]}_0}}}{{\left[ R \right]}} \cr & = \frac{{2.303}}{{\left( {\frac{{0.693}}{{5730}}} \right)}}\log \frac{{100}}{{80}} \cr & = \frac{{2.303 \times 5730}}{{0.693}} \times 0.0969 \cr & = 1845\,{\text{years}} \cr} $$

Releted MCQ Question on
Physical Chemistry >> Chemical Kinetics

Releted Question 1

If uranium (mass number 238 and atomic number 92) emits an $$\alpha $$ -particle, the product has mass no. and atomic no.

A. 236 and 92
B. 234 and 90
C. 238 and 90
D. 236 and 90
Releted Question 2

The rate constant of a reaction depends on

A. temperature
B. initial concentration of the reactants
C. time of reaction
D. extent of reaction
Releted Question 3

The specific rate constant of a first order reaction depends on the

A. concentration of the reactant
B. concentration of the product
C. time
D. temperature
Releted Question 4

A catalyst is a substance which

A. increases the equilibrium concentration of the product
B. changes the equilibrium constant of the reaction
C. shortens the time to reach equilibrium
D. supplies energy to the reaction

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Chemical Kinetics


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