Question

The formation of the oxide ion $$O_{\left( g \right)}^{2 - }$$ requires first an exothermic and then an endothermic step as shown below
$$\eqalign{ & {O_{\left( g \right)}} + {e^ - } = O_{\left( g \right)}^ - \,\,\Delta {H^ \circ } = - 142\,kJmo{l^{ - 1}} \cr & {O^ - }\left( g \right) + {e^ - } = O_{\left( g \right)}^{2 - }\,\,\Delta {H^ \circ } = 844\,kJmo{l^{ - 1}} \cr} $$
This is because

A. $${O^ - }$$ on will tend to resist the addition of another electron  
B. Oxygen has high electron affinity
C. Oxygen is more elecronegative
D. $${O^ - }$$ ion has comparatively larger size than oxygen atom
Answer :   $${O^ - }$$ on will tend to resist the addition of another electron
Solution :
$${O^ - }$$ ion exerts a force of repulsion on the incoming electron. The energy is required to overcome it.

Releted MCQ Question on
Inorganic Chemistry >> Classification of Elements and Periodicity in Properties

Releted Question 1

The correct order of second ionisation potential of carbon, nitrogen, oxygen and fluorine is

A. $$C > N > O > F$$
B. $$O > N > F > C$$
C. $$O > F > N > C$$
D. $$F > O > N > C$$
Releted Question 2

The element with the highest first ionization potential is

A. boron
B. carbon
C. nitrogen
D. oxygen
Releted Question 3

The first ionisation potential in electron volts of nitrogen and oxygen atoms are respectively given by

A. $$14.6,13.6\,$$
B. $$13.6,14.6$$
C. $$13.6,13.6$$
D. $$14.6,14.6$$
Releted Question 4

Atomic radii of fluorine and neon in $$\mathop {\text{A}}\limits^ \circ $$ngstorm units are respectively given by

A. $$0.72,1.60$$
B. $$1.60,1.60\,$$
C. $$0.72,0.72\,\,$$
D. None of these values

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Classification of Elements and Periodicity in Properties


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