Question

The density of gold is $$19\,g/c{m^3}.$$  If $$1.9 \times {10^{ - 4}}g$$   of gold is dispersed in one litre of water to give a sol having spherical gold particles of radius $$10\,nm,$$  then the number of gold particles per $$m{m^3}$$  of the sol will be :

A. $$1.9 \times {10^{12}}$$
B. $$6.3 \times {10^{14}}$$
C. $$6.3 \times {10^{10}}$$
D. $$2.4 \times {10^6}$$  
Answer :   $$2.4 \times {10^6}$$
Solution :
$$\eqalign{ & {\text{Volume of gold dispersed in }}1{\text{ }}L{\text{ water}} \cr & {\text{ = }}\frac{{mass}}{{Density}} = \frac{{1.9 \times {{10}^{ - 4}}g}}{{19gm\,c{m^{ - 3}}}} = 1 \times {10^{ - 5}}\,c{m^3} \cr & {\text{Radius of gold sol particle}} \cr & = 10\,nm = 10 \times {10^{ - 7}}\,cm = {10^{ - 6}}\,cm \cr & {\text{Volume of gol sol particle}} = \frac{4}{3}\pi {r^3} \cr & = \frac{4}{3} \times \frac{{22}}{7} \times {\left( {{{10}^{ - 6}}} \right)^3} = 4.19 \times {10^{ - 18}}c{m^3} \cr & \therefore \,\,{\text{No}}{\text{. of gold sol particles in}}\,\,1 \times {10^{ - 5}}c{m^3} \cr & = \frac{{1 \times {{10}^{ - 5}}}}{{4.19 \times {{10}^{ - 18}}}} = 2.38 \times {10^{12}} \cr & \therefore \,\,{\text{No}}{\text{. of gold sol particles in one}}\,m{m^3} \cr & = \frac{{2.38 \times {{10}^{12}}}}{{{{10}^6}}} \cr & = 2.38 \times {10^6} \cr} $$

Releted MCQ Question on
Physical Chemistry >> Surface Chemistry

Releted Question 1

Rate of physiorption increases with

A. decrease in temperature
B. increase in temperature
C. decrease in pressure
D. decrease in surface area
Releted Question 2

Adsorption of gases on solid surface is generally exothermic because

A. enthalpy is positive
B. entropy decreases
C. entropy increases
D. free energy increases
Releted Question 3

Lyophilic sols are

A. Irreversible sols
B. They are prepared from inorganic compound
C. Coagulated by adding electrolytes
D. Self-stabilizing
Releted Question 4

Among the following, the surfactant that will form micelles in aqueous solution at the lowest molar concentration at ambient condition is : -

A. $$C{H_3}{\left( {C{H_2}} \right)_{15}}{N^ + }{\left( {C{H_3}} \right)_3}B{r^ - }$$
B. $$C{H_3}{\left( {C{H_2}} \right)_{11}}OSO_3^ - N{a^ + }$$
C. $$C{H_3}{\left( {C{H_2}} \right)_6}CO{O^ - }N{a^ + }$$
D. $$C{H_3}{\left( {C{H_2}} \right)_{11}}{N^ + }{\left( {C{H_3}} \right)_3}B{r^ - }$$

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