Question

In three beakers labelled as $$(A), (B)$$   and $$(C),$$  $$100\,mL$$   of water, $$100\,mL$$   of $$1\,M$$  solution of glucose in water and $$100\,mL$$   of $$0.5\,M$$  solution of glucose in water are taken respectively and kept at same temperature.
Solutions mcq question image
Which of the following statements is correct ?

A. Vapour pressure in all the three beakers is same.
B. Vapour pressure of beaker $$B$$  is highest.
C. Vapour pressure of beaker $$C$$  is highest.
D. Vapour pressure of beaker $$B$$  is lower than that of $$C$$  and vapour pressure of beaker $$C$$  is lower than that of $$A.$$  
Answer :   Vapour pressure of beaker $$B$$  is lower than that of $$C$$  and vapour pressure of beaker $$C$$  is lower than that of $$A.$$
Solution :
Vapour pressure of a solution containing nonvolatile solute is less than that of the pure solvent. The decrease in vapour pressure depends upon the quantity of non-volatile solute present in it. Hence, vapour pressure of $$A > C > B.$$

Releted MCQ Question on
Physical Chemistry >> Solutions

Releted Question 1

An azeotropic solution of two liquids has boiling point lower than either of them when it

A. shows negative deviation from Raoult’s law
B. shows no deviation from Raoult’s law
C. shows positive deviation from Raoult’s law
D. is saturated
Releted Question 2

For a dilute solution, Raoult’s law states that :

A. the lowering of vapour pressure is equal to the mole fraction of solute.
B. the relative lowering of vapour pressure is equal to the mole fraction of solute.
C. the relative lowering of vapour pressure is proportional to the amount of solute in solution.
D. the vapour pressure of the solution is equal to the mole fraction of solvent.
Releted Question 3

When mercuric iodide is added to the aqueous solution of potassium iodide then

A. freezing point is raised.
B. freezing point is lowered.
C. freezing point does not change.
D. boiling point does not change.
Releted Question 4

Which of the following $$0.1 M$$  aqueous solutions will have the lowest freezing point?

A. Potassium sulphate
B. Sodium chloride
C. Urea
D. Glucose

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