if 3 hexanone is reacted with nabh4 followed by hydrolysis

If 3 - hexanone is reacted with \[NaB{{H}_{4}}\] followed by hydrolysis with \[{{D}_{2}}O,\] the product will be

A. $$C{H_3}C{H_2}CH\left( {OH} \right)C{H_2}C{H_2}C{H_3}$$

B. $$C{H_3}C{H_2}CD\left( {OH} \right)C{H_2}C{H_2}C{H_3}$$

C. $$C{H_3}C{H_2}CH\left( {OD} \right)C{H_2}C{H_2}C{H_3}$$

D. $$C{H_3}C{H_2}CD\left( {OD} \right)C{H_2}C{H_2}C{H_3}$$

Answer : $$C{H_3}C{H_2}CH\left( {OD} \right)C{H_2}C{H_2}C{H_3}$$

Solution :
Remember that during reduction with $$NaB{H_4},$$ a hydride ion is transferred by $$NaB{H_4}$$ to carbonyl carbon and a proton ( or deutron ) is transferred from the solvent ( in the second step ) to carbonyl oxygen.
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Organic Chemistry >> Aldehyde and Ketone

Releted Question 1

The reagent with which both acetaldehyde and acetone react easily is

A. Fehling’s reagent

B. Grignard reagent

C. Schiff’s reagent

D. Tollen’s reagent

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Releted Question 2

The Cannizzaro reaction is not given by

A. trimethylacetaldehye

B. acetaldehyde

C. benzaldehyde

D. formaldehyde

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Releted Question 3

The compound that will not give iodoform on treatment with alkali and iodine is :

A. acetone

B. ethanol

C. diethyl ketone

D. isopropyl alcohol

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Releted Question 4

Polarisation of electrons in acrolein may be written as

A. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - \mathop {CH}\limits^{{\delta ^ + }} = O$$

B. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - CH = \mathop O\limits^{{\delta ^ + }} $$

C. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = \mathop {CH}\limits^{{\delta ^ + }} - CH = O$$

D. $$\mathop {C{H_2}}\limits^{{\delta ^ + }} = CH - CH = \mathop O\limits^{{\delta ^ - }} $$

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If 3 - hexanone is reacted with \[NaB{{H}_{4}}\] followed by hydrolysis with \[{{D}_{2}}O,\] the product will be

Releted MCQ Question on
Organic Chemistry >> Aldehyde and Ketone

The reagent with which both acetaldehyde and acetone react easily is

The Cannizzaro reaction is not given by

The compound that will not give iodoform on treatment with alkali and iodine is :

Polarisation of electrons in acrolein may be written as

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Aldehyde and Ketone

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If 3 - hexanone is reacted with \[NaB{{H}_{4}}\] followed by hydrolysis with \[{{D}_{2}}O,\] the product will be

Releted MCQ Question on Organic Chemistry >> Aldehyde and Ketone

The reagent with which both acetaldehyde and acetone react easily is

The Cannizzaro reaction is not given by

The compound that will not give iodoform on treatment with alkali and iodine is :

Polarisation of electrons in acrolein may be written as

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Releted MCQ Question on
Organic Chemistry >> Aldehyde and Ketone

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Aldehyde and Ketone