Question

Identify the correct order of solubility of $$N{a_2}S,\,CuS\,{\text{and}}\,ZnS$$     in aqueous medium

A. $$CuS > ZnS > N{a_2}S$$
B. $$ZnS > N{a_2}S > CuS$$
C. $$N{a_2}S > CuS > ZnS$$
D. $$N{a_2}S > ZnS > CuS$$  
Answer :   $$N{a_2}S > ZnS > CuS$$
Solution :
Sodium salts are highly soluble. $$C{u^{2 + }}$$  belongs to the $$I{I^{{\text{nd}}}}$$  group in salt analysis and is precipitated as $$CuS,$$  whereas $$Z{n^{2 + }}$$  belongs to the $$IV$$  group and is precipitated as $$ZnS$$  after $$CuS$$  because of higher $${K_{sp}}$$ of $$ZnS.$$

Releted MCQ Question on
Inorganic Chemistry >> Qualitative Analysis

Releted Question 1

The ion that cannot be precipitated by both $$HCl\,{\text{and}}\,{H_2}S$$    is

A. $$P{b^{2 + }}$$
B. $$C{u^ + }$$
C. $$A{g^ + }$$
D. $$S{n^{2 + }}$$
Releted Question 2

Which one among the following pairs of ions cannot be separated by $${H_2}S$$  in dilute hydrochloric acid?

A. $$B{i^{3 + }},S{n^{4 + }}$$
B. $$A{l^{3 + }},H{g^{2 + }}$$
C. $$Z{n^{2 + }},C{u^{2 + }}$$
D. $$N{i^{2 + }},C{u^{2 + }}$$
Releted Question 3

An aqueous solution contains $$H{g^{2 + }},Hg_2^{2 + },P{b^{2 + }}\,{\text{and}}\,C{d^{2 + }}.$$
The addition of $$HCl\left( {6N} \right)$$   will precipitate:

A. $$H{g_2}C{l_2}\,{\text{only}}$$
B. $$PbC{l_2}\,{\text{only}}$$
C. $$PbC{l_2}\,{\text{and}}\,H{g_2}C{l_2}$$
D. $$PbC{l_2}\,{\text{and}}\,HgC{l_2}$$
Releted Question 4

Identify the correct order of solubility of $$N{a_2}S,\,CuS\,{\text{and}}\,ZnS$$     in aqueous medium

A. $$CuS > ZnS > N{a_2}S$$
B. $$ZnS > N{a_2}S > CuS$$
C. $$N{a_2}S > CuS > ZnS$$
D. $$N{a_2}S > ZnS > CuS$$

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