Question

How many grams of concentrated nitric acid solution should be used to prepare $$250 mL$$  of $$2.0\,M\,HN{O_3}?$$    The concentrated acid is $$70\% \,HN{O_3}.$$

A. $$45.0\,g\,conc.\,HN{O_3}$$  
B. $$90.0\,g\,conc.\,HN{O_3}$$
C. $$70.0g\,conc.\,HN{O_3}$$
D. $$54.0g\,conc.\,HN{O_3}$$
Answer :   $$45.0\,g\,conc.\,HN{O_3}$$
Solution :
$$\eqalign{ & {\text{Given, molarity of solution = 2}} \cr & {\text{Volume of solution}} \cr & = 250\,mL \cr & = \frac{{250}}{{1000}} \cr & = \frac{1}{4}L \cr & {\text{Molar mass of}} \cr & HN{O_3} = 1 + 14 + 3 \times 16 \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = 63\,g\,mo{l^{ - 1}} \cr & \because \,{\text{Molarity}} \cr & = \frac{{{\text{Weight of}}\,HN{O_3}}}{{{\text{Molecular mass of}}\,HN{O_3} \times {\text{volume of solution}}\,\left( L \right)}} \cr} $$

$$\therefore \,\,{\text{Weight of}}\,HN{O_3}$$     $$ = {\text{molarity}} \times {\text{molecular mass}} \times {\text{volume }}(L)$$
$$\eqalign{ & = 2 \times 63 \times \frac{1}{4}g \cr & = 31.5\,g \cr & {\text{It is the weight of }}100\% {\text{ }}HN{O_3} \cr & {\text{But the given acid is }}70\% {\text{ }}HN{O_3} \cr & \therefore \,\,{\text{Its weight}}\,{\text{ = }}\,{\text{31}}{\text{.5}} \times \frac{{100}}{{70}}\,g \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = 45\,g \cr} $$

Releted MCQ Question on
Physical Chemistry >> Some Basic Concepts in Chemistry

Releted Question 1

$$27 g$$  of $$Al$$  will react completely with how many grams of oxygen?

A. $$8\,g$$
B. $$16\,g$$
C. $$32\,g$$
D. $$24\,g$$
Releted Question 2

A compound was found to contain nitrogen and oxygen in the ratio $$28 gm$$  and $$80 gm$$  respectively. The formula of compound is

A. $$NO$$
B. $${N_2}{O_3}$$
C. $${N_2}{O_5}$$
D. $${N_2}{O_4}$$
Releted Question 3

The largest number of molecules is in

A. $$36\,g$$  of water
B. $$28\,g$$  of carbon monoxide
C. $$46\,g$$  of ethyl alcohol
D. $$54\,g$$  of nitrogen pentoxide
Releted Question 4

The total number of electrons in one molecule of carbon dioxide is

A. 22
B. 44
C. 66
D. 88

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