Question

Excess of $$KI$$  reacts with $$CuS{O_4}$$  solution and then $$N{a_2}{S_2}{O_3}$$   solution is added to it. Which of the statements is incorrect for this reaction ?

A. $$N{a_2}{S_2}{O_3}$$   is oxidised
B. $$Cu{I_2}$$  is formed  
C. $$C{u_2}{I_2}$$  is formed
D. Evolved $${I_2}$$  is reduced
Answer :   $$Cu{I_2}$$  is formed
Solution :
$$\eqalign{ & 4\mathop {KI}\limits^{ - 1} + 2CuS{O_4} \to \mathop {{I_2}}\limits^0 + C{u_2}{I_2} + 2{K_2}S{O_4} \cr & \mathop {{I_2}}\limits^0 + \mathop {2N{a_2}{S_2}{O_3}}\limits^{2 + } \to \mathop {N{a_2}{S_4}{O_6}}\limits^{ - 2.5} + 2N\mathop {aI}\limits^{ - 1} \cr & {\text{In this}}\,Cu{I_2}\,{\text{is not formed}}{\text{.}} \cr} $$

Releted MCQ Question on
Inorganic Chemistry >> P - Block Elements

Releted Question 1

The reddish brown coloured gas formed when nitric oxide is oxidised by air is

A. $${N_2}{O_5}$$
B. $${N_2}{O_4}$$
C. $$N{O_2}$$
D. $${N_2}{O_3}$$
Releted Question 2

The temporary hardness of water due to calcium carbonate can be removed by adding —

A. $$CaC{O_3}$$
B. $$Ca{\left( {OH} \right)_2}\,$$
C. $$CaC{l_2}$$
D. $$\,HCl$$
Releted Question 3

Which of the following is most stable to heat

A. $$HCl$$
B. $$HOCl$$
C. $$HBr$$
D. $$HI$$
Releted Question 4

White $$P$$ reacts with caustic soda. The products are $$P{H_3}$$ and $$Na{H_2}P{O_2}.$$   This reaction is an example of

A. Oxidation
B. Reduction
C. oxidation and reduction
D. Neutralisation

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