Question

During dehydration of alcohols to alkenes by heating with conc. \[{{H}_{2}}S{{O}_{4}}\]  the initiation step is

A. formation of carbocation
B. elimination of water
C. formation of an ester
D. protonation of alcohol molecule  
Answer :   protonation of alcohol molecule
Solution :
The dehydration of alcohol to form alkene occurs in following three step. Step (1) is initiation step.
Step (1) Formation of protonated alcohol.
Alcohol, Phenol and Ether mcq solution image
Step (2) Formation of carbocation
Alcohol, Phenol and Ether mcq solution image
Step (3) Elimination ofa proton to form ethene
Alcohol, Phenol and Ether mcq solution image

Releted MCQ Question on
Organic Chemistry >> Alcohol, Phenol and Ether

Releted Question 1

Ethyl alcohol is heated with conc $${H_2}S{O_4}$$  the product formed is

A. \[{{H}_{3}}C\underset{\begin{smallmatrix} \parallel \\ O \end{smallmatrix}}{\mathop{-C-}}\,O{{C}_{2}}{{H}_{5}}\]
B. $${C_2}{H_6}$$
C. $${C_2}{H_4}$$
D. $${C_2}{H_2}$$
Releted Question 2

The compound which reacts fastest with Lucas reagent at room temperature is

A. $${\text{butan - 1 - ol}}$$
B. $${\text{butan - 2 - ol}}$$
C. $${\text{2 - methylpropan - 1 - ol}}$$
D. $${\text{2 - methylpropan - 2 - ol}}$$
Releted Question 3

A compound that gives a positive iodoform test is

A. 1 - pentanol
B. 2 - pentanone
C. 3 - pentanone
D. pentanal
Releted Question 4

Diethyl ether on heating with conc. $$HI$$  gives two moles of $$H$$

A. ethanol
B. iodoform
C. ethyl iodide
D. methyl iodide

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Alcohol, Phenol and Ether


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