Question

\[CuS{{O}_{4}}\left( aq. \right)\xrightarrow{{{H}_{2}}S\uparrow }M\downarrow \xrightarrow[\text{of}\,KCN]{\text{Excess}}N+O\]
Then final products $$N$$  and $$O$$  are respectively.

A. $${\left[ {Cu{{\left( {CN} \right)}_4}} \right]^{3 - }},{\left( {CN} \right)_2}$$  
B. $$CuCN,{\left( {CN} \right)_2}$$
C. $${\left[ {Cu{{\left( {CN} \right)}_4}} \right]^{2 - }},{\left( {CN} \right)_2}$$
D. $$Cu{\left( {CN} \right)_2},{K_2}S$$
Answer :   $${\left[ {Cu{{\left( {CN} \right)}_4}} \right]^{3 - }},{\left( {CN} \right)_2}$$
Solution :
\[CuS{{O}_{4}}\left( aq. \right)\xrightarrow{{{H}_{2}}S}\underset{\begin{smallmatrix} \text{Black ppt}\text{.} \\ \left( M \right) \end{smallmatrix}}{\mathop{2CuS}}\,\xrightarrow[\text{Excess}]{KCN}{{\left[ \underset{\left( N \right)}{\mathop{Cu}}\,{{\left( CN \right)}_{4}} \right]}^{3-}}+\underset{\left( O \right)}{\mathop{{{\left( CN \right)}_{2}}}}\,\uparrow \]

Releted MCQ Question on
Inorganic Chemistry >> D and F Block Elements

Releted Question 1

When same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide, the ratio of volume of hydrogen evolved is

A. $$1:1$$
B. $$1:2$$
C. $$2:1$$
D. $$9:4$$
Releted Question 2

Which of the following is the weakest base

A. $$NaOH$$
B. $$Ca{\left( {OH} \right)_2}$$
C. $$KOH$$
D. $$Zn{\left( {OH} \right)_2}$$
Releted Question 3

One of the constituent of German silver is

A. $$Ag$$
B. $$Cu$$
C. $$Mg$$
D. $$Al$$
Releted Question 4

Which of the following dissolve in hot conc.$$NaOH$$  solution

A. $$Fe$$
B. $$Zn$$
C. $$Cu$$
D. $$Ag$$

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D and F Block Elements


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