Question

Consider the following statements with respect to lanthanides :
1. The basic strength of hydroxides of lanthanides increases from $$La{\left( {OH} \right)_3}$$  to $$Lu{\left( {OH} \right)_3}.$$
2. The lanthanide ions $$L{u^{3 + }},Y{b^{2 + }}$$   and $$C{e^{4 + }}$$  are diamagnetic.
Which of the statement$$(s)$$  given above is/are correct?

A. 1 only
B. 2 only  
C. Both 1 and 2
D. Neither 1 nor 2
Answer :   2 only
Solution :
Basic strength decreases from $$La{\left( {OH} \right)_3}$$  to $$Lu{\left( {OH} \right)_3}.$$
Hence, (1) is incorrect.
$$Ce = \left[ {Xe} \right]4{f^1}5{d^1}6{s^2};C{e^{4 + }}$$       $$ = \left[ {Xe} \right]$$
$$Yb = \left[ {Xe} \right]4{f^{14}}6{s^2};Y{b^{2 + }}$$      $$ = \left[ {Xe} \right]4{f^{14}}$$
$$Lu = \left[ {Xe} \right]4{f^{14}}5{d^1}6{s^2};L{u^{3 + }}$$      $$ = \left[ {Xe} \right]4{f^{14}}$$

Releted MCQ Question on
Inorganic Chemistry >> D and F Block Elements

Releted Question 1

When same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide, the ratio of volume of hydrogen evolved is

A. $$1:1$$
B. $$1:2$$
C. $$2:1$$
D. $$9:4$$
Releted Question 2

Which of the following is the weakest base

A. $$NaOH$$
B. $$Ca{\left( {OH} \right)_2}$$
C. $$KOH$$
D. $$Zn{\left( {OH} \right)_2}$$
Releted Question 3

One of the constituent of German silver is

A. $$Ag$$
B. $$Cu$$
C. $$Mg$$
D. $$Al$$
Releted Question 4

Which of the following dissolve in hot conc.$$NaOH$$  solution

A. $$Fe$$
B. $$Zn$$
C. $$Cu$$
D. $$Ag$$

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