Question

Consider the Arrhenius equation given below and mark the correct option.
$$k = A{e^{ - \frac{{{E_a}}}{{RT}}}}$$

A. Rate constant increases exponentially with increasing activation energy and decreasing temperature.
B. Rate constant decreases exponentially with increasing activation energy and decreasing temperature.
C. Rate constant increases exponentially with decreasing activation energy and decreasing temperature.
D. Rate constant increases exponentially with decreasing activation energy and increasing temperature.  
Answer :   Rate constant increases exponentially with decreasing activation energy and increasing temperature.
Solution :
$$k = A{e^{ - \frac{{{E_a}}}{{RT}}}}$$
On increasing temperature and decreasing activation energy $${\frac{{{E_a}}}{{RT}}}$$  term overall decreases thus, $${ - \frac{{{E_a}}}{{RT}}}$$  term increases and rate constant increases exponentially.

Releted MCQ Question on
Physical Chemistry >> Chemical Kinetics

Releted Question 1

If uranium (mass number 238 and atomic number 92) emits an $$\alpha $$ -particle, the product has mass no. and atomic no.

A. 236 and 92
B. 234 and 90
C. 238 and 90
D. 236 and 90
Releted Question 2

The rate constant of a reaction depends on

A. temperature
B. initial concentration of the reactants
C. time of reaction
D. extent of reaction
Releted Question 3

The specific rate constant of a first order reaction depends on the

A. concentration of the reactant
B. concentration of the product
C. time
D. temperature
Releted Question 4

A catalyst is a substance which

A. increases the equilibrium concentration of the product
B. changes the equilibrium constant of the reaction
C. shortens the time to reach equilibrium
D. supplies energy to the reaction

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Chemical Kinetics


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