521. When $$C{l_2}$$  gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from

A zero to + 1 and zero to - 5
B zero to - 1 and zero to + 5
C zero to - 1 and zero to + 3
D zero to + 1 and zero to - 3
Answer :   zero to - 1 and zero to + 5
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522. Anhydrous $$AlC{l_3}$$  is prepared by

A reaction of $$HCl$$  and $$Al$$  metal
B reaction of dry $$HCl$$  gas and heated $$Al$$  metal
C passing conc. $$HN{O_3}$$  gas over heated $$Al$$  metal
D reaction of $$A{l_2}{O_3}$$  with $$dil.\,HCl$$
Answer :   reaction of dry $$HCl$$  gas and heated $$Al$$  metal
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523. Which of the following pairs of ions are isoelectronic and isostructural?

A $$CO_3^{2 - },NO_3^ - $$
B $$ClO_3^ - ,CO_3^{2 - }$$
C $$SO_3^{2 - },NO_3^ - $$
D $$ClO_3^ - ,SO_3^{2 - }$$
Answer :   $$CO_3^{2 - },NO_3^ - $$
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524. Identify the incorrect statement among the following.

A $$B{r_2}$$  reacts with hot and strong $$NaOH$$  solution to give $$NaBr\,{\text{and}}\,{H_2}O$$.
B Ozone reacts with $$S{O_2}$$  to give $$S{O_3}$$ .
C Silicon reacts with $$NaO{H_{\left( {aq} \right)}}$$  in the presence of air to give $$N{a_2}Si{O_3}\,{\text{and}}\,{H_2}O$$.
D $$C{l_2}$$  reacts with excess of $$N{H_3}$$  to give $${N_2}$$  and $$HCl$$ .
Answer :   $$C{l_2}$$  reacts with excess of $$N{H_3}$$  to give $${N_2}$$  and $$HCl$$ .
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525. White $$P$$ reacts with caustic soda. The products are $$P{H_3}$$ and $$Na{H_2}P{O_2}.$$   This reaction is an example of

A Oxidation
B Reduction
C oxidation and reduction
D Neutralisation
Answer :   oxidation and reduction
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526. Group 16 elements have lower value of first ionisation enthalpy as compared to group 15 elements because

A half filled $$p$$ - orbitals in group 15 elements are more stable
B group 16 elements have smaller size than group 15 elements
C group 16 elements contain double bond while group 15 elements have triple bond
D group 16 elements have more number of electrons in $$p$$ - orbitals.
Answer :   half filled $$p$$ - orbitals in group 15 elements are more stable
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527. In case of nitrogen, $$NC{l_3}$$  is possible but not $$NC{l_5}$$  while in case of phosphorous, $$PC{l_3}$$  as well as $$PC{l_5}$$  are possible. It is due to

A availability of vacant $$d$$  orbitals in $$P$$  but not in $$N$$
B lower electronegativity of $$P\,{\text{than}}\,N$$
C lower tendency of $$H$$-bond formation in $$P\,{\text{than}}\,N$$
D occurrence of $$P$$  in solid while $$N$$  in gaseous state at room temperature.
Answer :   availability of vacant $$d$$  orbitals in $$P$$  but not in $$N$$
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528. Which of the following oxides of nitrogen is a coloured gas?

A $${N_2}O$$
B $$NO$$
C $${N_2}{O_5}$$
D $$N{O_2}$$
Answer :   $$N{O_2}$$
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529. Which of the following does not show electrical conduction?

A Potassium
B Graphite
C Diamond
D Sodium
Answer :   Diamond
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530. When three parts of cone. $$HCl$$  and one part of cone. $$HN{O_3}$$  is mixed, a compound $$'X'$$ is formed. The correct option related to $$'X'$$ is

A $$'X'$$ is known as aqua-regia
B $$'X'$$ is used for dissolving gold
C $$'X'$$ is used for decomposition of salts of weaker acids
D both (A) and (B)
Answer :   both (A) and (B)
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