Question

Arrange the van der Waals constant for the gases:
1. $${C_6}{H_{6\left( g \right)}}$$ a. 0.217
2. $${C_6}{H_5} \cdot C{H_{3\left( g \right)}}$$ b. 5.464
3. $$N{e_{\left( g \right)}}$$ c. 18.000
4. $${H_2}{O_{\left( g \right)}}$$ d. 24.060

A. 1-a, 2-d, 3-c, 4-b
B. 1-d, 2-a, 3-b, 4-c
C. 1-c, 2-d, 3-a, 4-b  
D. 1-b, 2-c, 3-a, 4-d
Answer :   1-c, 2-d, 3-a, 4-b
Solution :
NOTE : The value of $$'a'$$  indicates the magnitude of attractive forces between gas molecules.
Value of $$\,'a' \propto \,$$  size of molecule.
∴ inert gas will have minimum value of $$\,'a'$$  followed by $${H_2}O,\,{C_6}{H_6}$$   and $${C_6}{H_5}C{H_3}$$

Releted MCQ Question on
Physical Chemistry >> States of Matter Solid, Liquid and Gas

Releted Question 1

Equal weights of methane and oxygen are mixed in an empty container at $${25^ \circ }C.$$  The fraction of the total pressure exerted by oxygen is

A. $$\frac{1}{3}$$
B. $$\frac{1}{2}$$
C. $$\frac{2}{3}$$
D. $$\frac{1}{3} \times \frac{{273}}{{298}}$$
Releted Question 2

The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is

A. Critical temperature
B. Boyle temperature
C. Inversion temperature
D. Reduced temperature
Releted Question 3

The ratio of root mean square velocity to average velocity of a gas molecule at a particular temperature is

A. 1.086 : 1
B. 1 : 1.086
C. 2 : 1.086
D. 1.086 : 2
Releted Question 4

Helium atom is two times heavier than a hydrogen molecule. At $$298 K,$$  the average kinetic energy of a helium atom is

A. two times that of a hydrogen molecule.
B. same as that of a hydrogen molecule.
C. four times that of a hydrogen molecule.
D. half that of a hydrogen molecule.

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States of Matter Solid, Liquid and Gas


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