Question
Arrange the following compounds in increasing order of their boiling points.
Arrange the following compounds in increasing order of their boiling points.
$$\left( {\text{i}} \right)$$ 
\[\begin{align}
& \left( \text{ii} \right)C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}Br \\
& \left( \text{iii} \right){{H}_{3}}C\underset{\begin{smallmatrix}
| \\
\,Br
\end{smallmatrix}}{\overset{\begin{smallmatrix}
\,\,\,\,\,C{{H}_{3}} \\
|
\end{smallmatrix}}{\mathop{-C-}}}\,C{{H}_{3}} \\
\end{align}\]
A.
(ii) < (i) < (iii)
B.
(i) < (ii) < (iii)
C.
(iii) < (i) < (ii)
D.
(iii) < (ii) < (i)
Answer :
(iii) < (i) < (ii)
Solution :
Boiling point increases as the branching decreases.
Boiling point increases as the branching decreases.