Question

Among the following ethers which one will produce methyl alcohol on treatment with hot concentrated $$HI?$$

A. Alcohol, Phenol and Ether mcq option image
B. Alcohol, Phenol and Ether mcq option image
C. Alcohol, Phenol and Ether mcq option image  
D. Alcohol, Phenol and Ether mcq option image
Answer :   Alcohol, Phenol and Ether mcq option image
Solution :
The ether which gives more stable carbocation, forms $$C{H_3}OH$$  as one of the product with hot $$conc.$$  $$HI.$$  The order of stability of carbocation is
$${3^ \circ } > {2^ \circ } > {1^ \circ }$$
Thus, Alcohol, Phenol and Ether mcq solution image gives $$C{H_3}OH$$  as one of the product. The reaction proceeds as
Alcohol, Phenol and Ether mcq solution image

Releted MCQ Question on
Organic Chemistry >> Alcohol, Phenol and Ether

Releted Question 1

Ethyl alcohol is heated with conc $${H_2}S{O_4}$$  the product formed is

A. \[{{H}_{3}}C\underset{\begin{smallmatrix} \parallel \\ O \end{smallmatrix}}{\mathop{-C-}}\,O{{C}_{2}}{{H}_{5}}\]
B. $${C_2}{H_6}$$
C. $${C_2}{H_4}$$
D. $${C_2}{H_2}$$
Releted Question 2

The compound which reacts fastest with Lucas reagent at room temperature is

A. $${\text{butan - 1 - ol}}$$
B. $${\text{butan - 2 - ol}}$$
C. $${\text{2 - methylpropan - 1 - ol}}$$
D. $${\text{2 - methylpropan - 2 - ol}}$$
Releted Question 3

A compound that gives a positive iodoform test is

A. 1 - pentanol
B. 2 - pentanone
C. 3 - pentanone
D. pentanal
Releted Question 4

Diethyl ether on heating with conc. $$HI$$  gives two moles of $$H$$

A. ethanol
B. iodoform
C. ethyl iodide
D. methyl iodide

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Alcohol, Phenol and Ether


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