Question

According to IUPAC nomenclature sodium nitroprusside is named as

A. sodium pentacyanonitrosyl ferrate (II)
B. sodium pentacyanonitrosyl ferrate (III)  
C. sodium nitroferricyanide
D. sodium nitroferrocyanide
Answer :   sodium pentacyanonitrosyl ferrate (III)
Solution :
IUPAC name of sodium nitroprusside $$N{a_2}\left[ {Fe{{\left( {CN} \right)}_5}NO} \right]$$    is sodium pentacyanoni trosyl ferrate (III) because in it $$NO$$  is neutral ligand and the oxidation number of $$Fe$$  is + 3. Which is calculated as
$$\eqalign{ & N{a_2}\left[ {Fe{{\left( {CN} \right)}_5}NO} \right] \cr & 2 \times \left( { + 1} \right) + x + 5 \times \left( { - 1} \right) + 1 \times 0 = 0 \cr & \,\,\,\,\,\,{\text{[where }}x{\text{ }} = {\text{ oxidation state of }}Fe{\text{]}} \cr & 2 + x - 5 = 0 \cr & \,\,\,\,\,\,\,\,\,x - 3 = 0 \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x = + 3 \cr} $$

Releted MCQ Question on
Inorganic Chemistry >> Co - ordination Compounds

Releted Question 1

Amongst $$Ni{\left( {CO} \right)_4},{\left[ {Ni{{\left( {CN} \right)}_4}} \right]^{2 - }}{\text{and}}\,NiCl_4^{2 - }$$

A. $$Ni{\left( {CO} \right)_4}\,{\text{and}}\,NiCl_4^{2 - }$$     are diamagnetic and $${\left[ {Ni{{\left( {CN} \right)}_4}} \right]^{2 - }}$$   is paramagnetic
B. $$NiCl_4^{2 - }\,{\text{and}}\,{\left[ {Ni{{\left( {CN} \right)}_4}} \right]^{2 - }}$$     are diamagnetic and $$Ni{\left( {CO} \right)_4}$$   is paramagnetic
C. $$Ni{\left( {CO} \right)_4}\,{\text{and}}\,{\left[ {Ni{{\left( {CN} \right)}_4}} \right]^{2 - }}$$     are diamagnetic and $$NiCl_4^{2 - }$$  is paramagnetic
D. $$Ni{\left( {CO} \right)_4}$$  is diamagnetic and $$NiCl_4^{2 - }\,{\text{and}}\,{\left[ {Ni{{\left( {CN} \right)}_4}} \right]^{2 - }}$$     are paramagnetic
View Answer
Releted Question 2

The geometry of $$Ni{\left( {CO} \right)_4}\,{\text{and}}\,Ni{\left( {PP{h_3}} \right)_2}C{l_2}\,{\text{are}}$$

A. both square planar
B. tetrahedral and square planar, respectively
C. both tetrahedral
D. square planar and tetrahedral, respectively
View Answer
Releted Question 3

The complex ion which has no $$'d'$$ electron in the central metal atom is

A. $${\left[ {Mn{O_4}} \right]^ - }$$
B. $${\left[ {Co{{\left( {N{H_3}} \right)}_6}} \right]^{3 + }}$$
C. $${\left[ {Fe{{\left( {CN} \right)}_6}} \right]^{3 - }}$$
D. $${\left[ {Cr{{\left( {{H_2}O} \right)}_6}} \right]^{3 + }}$$
View Answer
Releted Question 4

In the process of extraction of gold,
Roasted gold ore $$ + C{N^ - } + {H_2}O\mathop \to \limits^{{O_2}} \left[ X \right] + O{H^ - }$$
$$\left[ X \right] + Zn \to \left[ Y \right] + Au$$
Identify the complexes $$\left[ X \right]\,\,{\text{and}}\,\,\left[ Y \right]$$

A. $$X = {\left[ {Au{{\left( {CN} \right)}_2}} \right]^ - },Y = {\left[ {Zn{{\left( {CN} \right)}_4}} \right]^{2 - }}$$
B. $$X = {\left[ {Au{{\left( {CN} \right)}_4}} \right]^{3 - }},Y = {\left[ {Zn{{\left( {CN} \right)}_4}} \right]^{2 - }}$$
C. $$X = {\left[ {Au{{\left( {CN} \right)}_2}} \right]^ - },Y = {\left[ {Zn{{\left( {CN} \right)}_6}} \right]^{4 - }}$$
D. $$X = {\left[ {Au{{\left( {CN} \right)}_4}} \right]^ - },Y = {\left[ {Zn{{\left( {CN} \right)}_4}} \right]^{2 - }}$$
View Answer

Practice More Releted MCQ Question on
Co - ordination Compounds

Practice More MCQ Question on Chemistry Section

Physical ChemistrySome Basic Concepts in ChemistryStoichiometryStates of Matter Solid, Liquid and GasAtomic StructureChemical ThermodynamicsSolutionsSolid StateSurface ChemistryChemical EquilibriumIonic EquilibriumChemical KineticsRedox ReactionElectrochemistryNuclear Chemistry
Inorganic ChemistryChemical Bonding and Molecular StructureOres and MetallurgyClassification of Elements and Periodicity in PropertiesHydrogenS - Block ElementsP - Block ElementsD and F Block ElementsCo - ordination CompoundsQualitative AnalysisPreparation and Properties of CompoundsEnvironmental Chemistry
Organic ChemistryGeneral Organic ChemistryIsomerismPurification and Characterisation of Organic CompoundsHydrocarbons (Alkane, Alkene and Alkyne)Aromatic hydrocarbonElectrophilic Aromatic Substitution (Haloalkanes and Haloarenes)Alkyl and Aryl HalideReactions on BenzeneAlcohol, Phenol and EtherAldehyde and KetoneCarboxylic AcidOrganic Compounds Containing NitrogenName ReactionsPolymersBiomoleculesChemistry in Everyday LifePractical Organic Chemistry