Question

A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will

A. increase by a factor of 4  
B. double
C. remain unchanged
D. triple
Answer :   increase by a factor of 4
Solution :
Since the reaction is 2nd order $$w.r.t$$  $$CO,$$ Thus, rate law is given as.
$$r = k{\left[ {CO} \right]^2}$$
Let initial concentration of $$CO$$  is a i.e. $$[CO]=a$$
$$\therefore \,\,{r_1} = k{\left( a \right)^2} = k{a^2}$$
when concentration becomes doubled, i.e.$$[CO] =2a$$
$$\therefore \,\,{r_2} = k{\left( {2a} \right)^2} = 4k{a^2}\,\,\,\therefore {r_2} = 4{r_1}$$
So, the rate of reaction becomes 4 times.

Releted MCQ Question on
Physical Chemistry >> Chemical Kinetics

Releted Question 1

If uranium (mass number 238 and atomic number 92) emits an $$\alpha $$ -particle, the product has mass no. and atomic no.

A. 236 and 92
B. 234 and 90
C. 238 and 90
D. 236 and 90
Releted Question 2

The rate constant of a reaction depends on

A. temperature
B. initial concentration of the reactants
C. time of reaction
D. extent of reaction
Releted Question 3

The specific rate constant of a first order reaction depends on the

A. concentration of the reactant
B. concentration of the product
C. time
D. temperature
Releted Question 4

A catalyst is a substance which

A. increases the equilibrium concentration of the product
B. changes the equilibrium constant of the reaction
C. shortens the time to reach equilibrium
D. supplies energy to the reaction

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Chemical Kinetics


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