Question

A gas undergoes change from state $$A$$ to state $$B.$$ In this process, the heat absorbed and work done by the gas is $$5\,J$$  and $$8\,J,$$  respectively. Now gas is brought back to $$A$$ by another process during which $$3\,J$$ of heat is evolved. In this reverse process of $$B$$  to $$A$$ :

A. $$10\,J$$  of the work will be done by the gas.
B. $$6\,J$$  of the work will be done by the gas.
C. $$10\,J$$  of the work will be done by the surrounding on gas.
D. $$6\,J$$  of the work will be done by the surrounding on gas.  
Answer :   $$6\,J$$  of the work will be done by the surrounding on gas.
Solution :
Chemical Thermodynamics mcq solution image
$$\eqalign{ & \Delta {U_{AB}} = q + w = + 5 + \left( { - 8} \right) = - 3 \cr & q = - 3,\,\Delta {U_{BA}} = + 3 \cr & \,\Delta {U_{BA}} = q + w \cr & \Rightarrow 3 = - 3 + w \Rightarrow w = + 6\,J\,{\text{(work done on the system)}}{\text{.}} \cr} $$

Releted MCQ Question on
Physical Chemistry >> Chemical Thermodynamics

Releted Question 1

The difference between heats of reaction at constant pressure and constant volume for the reaction : $$2{C_6}{H_6}\left( l \right) + 15{O_{2\left( g \right)}} \to $$     $$12C{O_2}\left( g \right) + 6{H_2}O\left( l \right)$$     at $${25^ \circ }C$$  in $$kJ$$ is

A. $$-$$ 7.43
B. $$+$$ 3.72
C. $$-$$ 3.72
D. $$+$$ 7.43
Releted Question 2

For which change $$\Delta H \ne \Delta E\,:$$

A. $${H_{2\left( g \right)}} + {I_{2\left( g \right)}} \to 2HI\left( g \right)$$
B. $$HC{\text{l}} + NaOH \to NaC{\text{l}}$$
C. $${C_{\left( s \right)}} + {O_{{2_{\left( g \right)}}}} \to C{o_{{2_{\left( g \right)}}}}$$
D. $${N_2}\left( g \right) + 3{H_2}\left( g \right) \to 2N{H_3}\left( g \right)$$
Releted Question 3

$${\text{The}}\,\Delta H_f^0\,{\text{for}}\,C{O_2}\left( g \right),\,CO\left( g \right)\,$$     and $${H_2}O\left( g \right)$$   are $$-393.5,$$  $$-110.5$$  and $$ - 241.8\,kJ\,mo{l^{ - 1}}$$    respectively. The standard enthalpy change ( in $$kJ$$ ) for the reaction $$C{O_2}\left( g \right) + {H_2}\left( g \right) \to CO\left( g \right) + {H_2}O\left( g \right)\,{\text{is}}$$

A. 524.1
B. 41.2
C. -262.5
D. -41.2
Releted Question 4

In thermodynamics, a process is called reversible when

A. surroundings and system change into each other.
B. there is no boundary between system and surroundings.
C. the surroundings are always in equilibrium with the system.
D. the system changes into the surroundings spontaneously.

Practice More Releted MCQ Question on
Chemical Thermodynamics


Practice More MCQ Question on Chemistry Section