Question

A compound $$X$$ decolourises $$B{r_2}$$  water and reacts slowly with conc. $${H_2}S{O_4}$$  to givean addition product. $$X$$ reacts with $$HBr$$  to form $$Y.$$ $$Y$$ reacts with $$NaOH$$  to form $$Z.$$ On oxidation $$Z$$ gives hexan-3-one. $$X, Y$$  and $$Z$$ in the reactions are
Hydrocarbons (Alkane, Alkene and Alkyne) mcq question image
\[X\xrightarrow{HBr}Y\xrightarrow{NaOH}Z\xrightarrow{\left[ O \right]}\]     \[\underset{\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\parallel \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O \\ & \,\,\,\,\,\,\,\,\,\,\,\text{Hexan-3-one} \\ & \\ \end{align}}{\mathop{C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-C-C{{H}_{2}}C{{H}_{3}}}}\,\]

A. $$X = C{H_3}C{H_2}CH = CHC{H_3},$$       $$Y = C{H_3}C{H_2}CH\left( {Br} \right)CH\left( {Br} \right)C{H_2}C{H_3},$$         $$Z = C{H_3}C{H_2}C{H_3}$$
B. $$X = C{H_3}CH = CHC{H_3},$$      $$Y = C{H_3}CH\left( {Br} \right)CH\left( {Br} \right)C{H_3},$$       $$Z = C{H_3}C{H_2}C{H_2}OH$$
C. $$X = C{H_3}C{H_2}CH = CHC{H_2}C{H_3},$$       \[Y=C{{H}_{3}}C{{H}_{2}}\underset{\begin{smallmatrix} |\,\,\,\,\, \\ Br\,\,\,\, \end{smallmatrix}}{\mathop{-CH-}}\,C{{H}_{2}}C{{H}_{2}}C{{H}_{3}},\]        \[Z=C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}\underset{\begin{smallmatrix} |\,\,\,\,\, \\ OH\,\,\,\, \end{smallmatrix}}{\mathop{-CH-}}\,C{{H}_{2}}C{{H}_{3}}\]  
D. $$X = C{H_3}C{H_2}C{H_2}CH = CHC{H_3},$$       $$Y = C{H_3}C{H_2}C{H_2}C{H_2}C{H_2}C{H_2}Br,$$        $$Z = C{H_3}C{H_2}C{H_2}C{H_2}OH$$
Answer :   $$X = C{H_3}C{H_2}CH = CHC{H_2}C{H_3},$$       \[Y=C{{H}_{3}}C{{H}_{2}}\underset{\begin{smallmatrix} |\,\,\,\,\, \\ Br\,\,\,\, \end{smallmatrix}}{\mathop{-CH-}}\,C{{H}_{2}}C{{H}_{2}}C{{H}_{3}},\]        \[Z=C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}\underset{\begin{smallmatrix} |\,\,\,\,\, \\ OH\,\,\,\, \end{smallmatrix}}{\mathop{-CH-}}\,C{{H}_{2}}C{{H}_{3}}\]
Solution :
Hydrocarbons (Alkane, Alkene and Alkyne) mcq solution image

Releted MCQ Question on
Organic Chemistry >> Hydrocarbons (Alkane, Alkene and Alkyne)

Releted Question 1

Marsh gas mainly contains

A. $${C_2}{H_2}$$
B. $$C{H_4}$$
C. $${H_2}S$$
D. $$CO$$
Releted Question 2

Which of the following decolourises alkaline $$KMn{O_4}$$

A. $${C_3}{H_8}$$
B. $${C_2}{H_4}$$
C. $$C{H_4}$$
D. $$CC{l_4}$$
Releted Question 3

The compound with the highest boiling point is

A. $$n $$ - hexane
B. $$n $$ - pentane
C. 2, 2 - dimethylpropane
D. 2 - methylbutane
Releted Question 4

The maximum number of isomers for an alkene with the molecular formula $${C_4}{H_8}$$  is

A. 2
B. 3
C. 4
D. 5

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