Question
$$1.0 g$$ of magnesium is burnt with $$0.56 g$$ of oxygen in a closed vessel. Which reactant is left in excess and how much?
$$\left( {{\text{At}}{\text{. weight of}}\,Mg = 24,\,O = 16} \right)$$
A.
$$Mg,\,0.16\,g$$
B.
$${O_2},\,0.16\,g$$
C.
$$Mg,\,0.44\,g$$
D.
$${O_2},\,0.28\,g$$
Answer :
$$Mg,\,0.16\,g$$
Solution :
The balanced chemical equation is
\[\underset{\begin{smallmatrix}
\\
24\,g
\end{smallmatrix}}{\mathop{Mg}}\,+\underset{16\,g}{\mathop{\frac{1}{2}{{O}_{2}}}}\,\to \underset{\begin{smallmatrix}
\\
40\,g
\end{smallmatrix}}{\mathop{MgO}}\,\]
From the above equation, it is clear that,
$$24 g$$ of $$Mg$$ reacts with $$16 g$$ of $${{O_2}}$$.
Thus, $$1.0$$ $$g$$ of $$Mg$$ reacts with
$$\frac{{16}}{{24}}g\,\,{\text{of}}\,{O_2} = 0.67\,g\,{\text{of}}\,{O_2}.$$
But only $$0.56 g$$ of $${{O_2}}$$ is available which is less than $$0.67 g.$$ Thus $${O_2}$$ is the limiting reagent.
Further, $$16$$ $$g$$ of $${{O_2}}$$ reacts with $$24 g$$ of $$Mg.$$
∴ $$0.56 g$$ of $${{O_2}}$$ will react with
$$\eqalign{
& Mg = \frac{{24}}{{16}} \times 0.56 \cr
& \,\,\,\,\,\,\,\,\,\, = 0.84\,g \cr} $$
∴ Amount of $$Mg$$ left unreacted
$$\eqalign{
& = \left( {1.0 - 0.84} \right)g\,\,Mg \cr
& = 0.16\,g\,Mg \cr} $$