Question
An ideal gas undergoes a quasi static, reversible process in which its molar heat capacity $$C$$ remains constant. If during this process the relation of pressure $$P$$ and volume $$V$$ is given by $$P{V^n}$$ = constant, then $$n$$ is given by (Here $${C_P}$$ and $${C_V}$$ are molar specific heat at constant pressure and constant volume, respectively):
A.
$$n = \frac{{{C_P} - C}}{{C - {C_V}}}\,$$
B.
$$n = \frac{{C - {C_V}}}{{C - {C_P}}}\,$$
C.
$$n = \frac{{{C_P}}}{{{C_V}}}\,$$
D.
$$n = \frac{{C - {C_P}}}{{C - {C_V}}}\,$$
Answer :
$$n = \frac{{C - {C_P}}}{{C - {C_V}}}\,$$
Solution :
For a polytropic process
$$\eqalign{
& C = {C_V} + \frac{R}{{1 - n}} \cr
& \therefore \,\,C - {C_V} = \frac{R}{{1 - n}} \cr
& \therefore \,\,1 - n = \frac{R}{{C - {C_V}}} \cr
& \therefore \,\,1 - \frac{R}{{C - {C_V}}} = n \cr
& \therefore \,\,n = \frac{{C - {C_V} - R}}{{C - {C_V}}} \cr
& = \frac{{C - {C_V} - {C_P} + {C_V}}}{{C - {C_V}}} \cr
& = \frac{{C - {C_P}}}{{C - {C_V}}}\,\left( {\because \,{C_P} - {C_{V = R}}} \right) \cr} $$